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Identify the correct statement...

Identify the correct statement

A

Lead forms compounds in +2 oxidation state due to inert pair effect

B

All halogens form only negative oxidation states

C

Catenation property increases from boron to oxygen

D

Oxygen's oxidation state is - 1 in ozonides

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question of identifying the correct statement among the given options, we will analyze each statement step by step. ### Step-by-Step Solution: 1. **Analyzing the First Statement**: - The first statement claims that lead forms compounds in the +2 oxidation state due to the inert pair effect. - Lead (Pb) has an atomic number of 82 and belongs to the carbon family (Group 14). - Its electronic configuration is [Xe] 6s² 6p². - The inert pair effect refers to the tendency of the s-electrons (in this case, the 6s² electrons) to remain unshared in compounds, leading to a more stable +2 oxidation state compared to +4. - Therefore, this statement is **true**. 2. **Analyzing the Second Statement**: - The second statement asserts that all halogens form only negative oxidation states. - While halogens typically have a -1 oxidation state, they can also exhibit positive oxidation states. - For example, bromine (Br) can have a +3 oxidation state in compounds like BrF₃. - Hence, this statement is **false**. 3. **Analyzing the Third Statement**: - The third statement suggests that catenation property increases from boron to oxygen. - Catenation is the ability of an element to form chains of atoms through covalent bonds. - Carbon exhibits the highest catenation ability, while oxygen has a much lower catenation property. - Thus, this statement is **false**. 4. **Analyzing the Fourth Statement**: - The fourth statement claims that the oxidation state of oxygen in ozonide (O₃⁻) is -1. - In ozonide, the total charge is -1, and since there are three oxygen atoms, the average oxidation state of each oxygen atom is -1/3. - Therefore, this statement is **false**. ### Conclusion: After analyzing all statements, the only correct statement is the first one regarding lead and the inert pair effect. Thus, the correct answer is: **Option A: Lead forms compounds in +2 oxidation state due to inert pair effect.**
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