Home
Class 12
CHEMISTRY
C6H6overset(CH3COCl)underset(AlCl3)rarro...

`C_6H_6overset(CH_3COCl)underset(AlCl_3)rarroverset(Zn//Hg//HCl)rarr(P)`
In the reaction sequence product (P) will be

A

`C_6H_5-CH_3`

B

`C_6H_5-CH_2-CH_3`

C

`C_6H_5-CH_2-CHO`

D

`C_6H_5-CH=CH_2`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the given reaction step by step. ### Step 1: Identify the Reactants The reactants are benzene (C₆H₆) and acetyl chloride (CH₃COCl) in the presence of aluminum chloride (AlCl₃). ### Step 2: Friedel-Crafts Acylation The reaction of benzene with acetyl chloride in the presence of aluminum chloride is a Friedel-Crafts acylation reaction. In this reaction, the acetyl chloride reacts with aluminum chloride to form an acylium ion (CH₃C^+=O). **Reaction:** \[ \text{C}_6\text{H}_6 + \text{CH}_3\text{COCl} \xrightarrow{\text{AlCl}_3} \text{C}_6\text{H}_5\text{COCH}_3 + \text{HCl} \] ### Step 3: Formation of the Product from Friedel-Crafts Acylation The acylium ion (CH₃C^+=O) acts as an electrophile and attacks the benzene ring, resulting in the formation of acetophenone (C₆H₅COCH₃). ### Step 4: Reduction with Zinc Amalgam and HCl The next step involves the reduction of the acetophenone product using zinc amalgam (Zn/Hg) and hydrochloric acid (HCl). This reduction converts the carbonyl group (C=O) of acetophenone into a methylene group (–CH₂–). **Reaction:** \[ \text{C}_6\text{H}_5\text{COCH}_3 \xrightarrow{\text{Zn/Hg/HCl}} \text{C}_6\text{H}_5\text{CH}_2\text{CH}_3 \] ### Step 5: Final Product The final product (P) obtained after the reduction is ethylbenzene (C₆H₅CH₂CH₃). ### Conclusion Therefore, the product (P) of the reaction sequence is: \[ \text{C}_6\text{H}_5\text{CH}_2\text{CH}_3 \] ---
Promotional Banner

Similar Questions

Explore conceptually related problems

2CH_(3)-underset(O)underset(||)(C)-CH_(3) underset(H^(+))overset(Mg//Hg)to Product in the reaction is

Complete the following : (i) C_(6)H_(5)COCH_(3)overset(Zn//Hg//HCl)rarr

Consider the following sequence of reactions overset(H^(+)//Delta)rarr (X)overset(1.0_(3))underset(2.Zn//CH_(3)COOH)rarr (Y) overset(NaOH)underset(Delta)rarr The intermediate products (X) and (Y) are respectively

Consider the following reaction sequence, CH_(3)C-= CH overset(aq.H_(2)SO_(4))underset(Hg SO_(4))rarr A overset(PCl_(5))underset(Heat)rarrB The products (A) and (B) are, respectively,

"But-1-ene"overset((CH_(3)COO)_(2)Hg)underset(H_(3)O)rarr? The product in the above reaction is

In the reaction sequence C_6H_5CHOoverset(NaCN//HCl)rarr(X)overset(H_2"O"//H^o+)rarr product, Product will be

In a set of the given reactions, acetic acid yielded a product iC. CH_(3)COOH+PCl_(5) to A overset(C_(6)H_(6))underset(Anh. AlCl_(3))toB overset(C_(2)H_(5)MgBr)underset("ether")toC Product C would be

underset(DMSO)overset(KCN)rarroverset(H_(2), Pd)rarr product is

overset(Zn-Hg.HCl)underset(Delta)to product of the reaction will be:

In the given reaction, CH_(3)-underset(CH_3)underset(|)(CH)-overset(O)overset(||)(C )-CH_2-CH_3 overset(CF_3CO_3H)(rarr)(X) as main product, 'X' will be