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The hybrid state and oxidation state of ...

The hybrid state and oxidation state of S in `SF_4` are respectively

A

`sp^3,+4`

B

`sp^2,+6`

C

`sp^3d,+4`

D

`dsp^3,+6`

Text Solution

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The correct Answer is:
To determine the hybrid state and oxidation state of sulfur (S) in sulfur tetrafluoride (SF₄), we can follow these steps: ### Step 1: Determine the Hybrid State of Sulfur in SF₄ 1. **Identify the Valence Electrons of Sulfur**: Sulfur (S) is in group 16 of the periodic table and has 6 valence electrons. 2. **Count the Number of Surrounding Atoms**: In SF₄, sulfur is surrounded by 4 fluorine (F) atoms. 3. **Use the Hybridization Formula**: The formula to determine the hybridization is: \[ \text{Hybridization} = \frac{1}{2} \left( \text{Valence Electrons} + \text{Number of Monovalent Atoms} \right) \] Here, the valence electrons of sulfur are 6, and there are 4 fluorine atoms (monovalent). Plugging in the values: \[ \text{Hybridization} = \frac{1}{2} \left( 6 + 4 \right) = \frac{10}{2} = 5 \] 4. **Determine the Hybridization Type**: A hybridization state of 5 corresponds to \( sp^3d \). ### Step 2: Determine the Oxidation State of Sulfur in SF₄ 1. **Set Up the Equation for Oxidation State**: Let the oxidation state of sulfur be \( x \). The oxidation state of fluorine is -1. 2. **Write the Equation**: Since there are 4 fluorine atoms, the equation can be set up as: \[ x + 4(-1) = 0 \] Simplifying this gives: \[ x - 4 = 0 \] Thus, \( x = +4 \). ### Final Answer The hybrid state and oxidation state of sulfur in SF₄ are: - Hybrid State: \( sp^3d \) - Oxidation State: +4 ### Summary The correct answer is \( sp^3d \) and +4.
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