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Silver cyanide overset(Delta)rarr"Silver...

Silver cyanide `overset(Delta)rarr"Silver"+Aoverset(OH^-)rarrX+Y+H_2O` In the above sequence of reaction A,X,Y are respectively.

A

`Cbar(N),(CN)_2,HCN`

B

`(CN)_2,CbarN,OCbarN`

C

`(CN)_2,N_2OCN`

D

`(CN)_2,C_2^(2-),NO_2^-`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the sequence of reactions involving silver cyanide (AgCN) and identify the compounds A, X, and Y. ### Step-by-Step Solution: 1. **Identify the Reaction of Silver Cyanide on Heating**: - When silver cyanide (AgCN) is heated, it decomposes into silver (Ag) and another compound. The decomposition reaction can be represented as: \[ 2 \text{AgCN} \xrightarrow{\Delta} 2 \text{Ag} + \text{C}_2\text{N}_2 \] - Here, the compound formed is dicyan (C₂N₂), which is represented as A. 2. **Treatment of Compound A with Hydroxide Ion (OH⁻)**: - The next step involves treating compound A (C₂N₂) with hydroxide ions (OH⁻). The reaction can be represented as: \[ \text{C}_2\text{N}_2 + \text{OH}^- \rightarrow \text{CN}^- + \text{OCN}^- + \text{H}_2\text{O} \] - In this reaction, the products formed are cyanide ion (CN⁻) and isocyanate ion (OCN⁻). 3. **Identify the Compounds**: - From the above reactions, we can summarize: - A (the compound formed after heating AgCN) is **C₂N₂**. - X (the cyanide ion produced) is **CN⁻**. - Y (the isocyanate ion produced) is **OCN⁻**. ### Final Answer: - A = C₂N₂ - X = CN⁻ - Y = OCN⁻
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