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What is not applicable to TeCl4 ?...

What is not applicable to `TeCl_4` ?

A

The molecule is Sea - saw shaped

B

It is tetrahedral in shape

C

It has 4 bond pair and 1 lone pair of electron

D

The hybrid state of Te is `sp^3d`

Text Solution

AI Generated Solution

The correct Answer is:
To determine what is not applicable to \( \text{TeCl}_4 \) (Tellurium Tetrachloride), we will analyze its electronic configuration, bonding, and geometry step by step. ### Step 1: Identify the Group and Valence Electrons - Tellurium (Te) belongs to Group 16 of the periodic table, which includes elements like Oxygen, Sulfur, Selenium, and Polonium. - As a Group 16 element, Tellurium has 6 valence electrons. **Hint:** Remember that elements in the same group of the periodic table have similar properties, including the number of valence electrons. ### Step 2: Determine Bonding with Chlorine - In \( \text{TeCl}_4 \), Tellurium forms bonds with 4 Chlorine atoms. - Since it has 6 valence electrons and forms 4 bonds, 4 of these electrons are used for bonding. **Hint:** The number of bonds formed by an element can often be determined by the number of valence electrons it has. ### Step 3: Calculate Lone Pairs - After forming 4 bonds with Chlorine, Tellurium will have 2 remaining valence electrons. - These 2 electrons will form 1 lone pair. **Hint:** The lone pairs are the electrons that are not involved in bonding and can affect the shape of the molecule. ### Step 4: Determine Steric Number - The steric number is calculated as the number of bond pairs plus the number of lone pairs. - In \( \text{TeCl}_4 \), there are 4 bond pairs (from the 4 \( \text{Te-Cl} \) bonds) and 1 lone pair. - Therefore, the steric number is \( 4 + 1 = 5 \). **Hint:** The steric number helps in predicting the hybridization and geometry of the molecule. ### Step 5: Determine Hybridization - A steric number of 5 indicates that the hybridization is \( \text{sp}^3\text{d} \). - This involves one s orbital, three p orbitals, and one d orbital. **Hint:** Hybridization can be determined based on the steric number, which reflects the number of regions of electron density around the central atom. ### Step 6: Determine Molecular Geometry - The geometry corresponding to \( \text{sp}^3\text{d} \) hybridization is trigonal bipyramidal. - With one lone pair, the molecular shape becomes seesaw. **Hint:** The presence of lone pairs can distort the ideal geometry, leading to different molecular shapes. ### Conclusion From the analysis, we can conclude: - The geometry of \( \text{TeCl}_4 \) is not tetrahedral; it is trigonal bipyramidal with a seesaw shape due to the lone pair. - Therefore, the statement that \( \text{TeCl}_4 \) is tetrahedral is **not applicable**. ### Final Answer The option that is not applicable to \( \text{TeCl}_4 \) is that it is tetrahedral in shape.
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