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In the reaction sequence CH3CHOoverset(N...

In the reaction sequence `CH_3CHOoverset(NH_2OH//overset(o+)H)rarr(A)overset(P_2O_5//Delta)rarr(B)`, B will be

A

`CH_3CH=NOH`

B

`H_2C=NOH`

C

`CH_3CN`

D

`CH_3CH_2NH_2`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will analyze the reaction sequence step by step. 1. **Identify the starting compound**: The starting compound is CH₃CHO, which is acetaldehyde. 2. **First reaction with NH₂OH**: When acetaldehyde (CH₃CHO) reacts with hydroxylamine (NH₂OH) in the presence of an acid (H⁺), it forms an oxime. The reaction can be represented as: \[ \text{CH}_3\text{CHO} + \text{NH}_2\text{OH} \rightarrow \text{CH}_3\text{C}=\text{N-OH} + \text{H}_2\text{O} \] The product formed is CH₃C=N-OH, which is called acetaldehyde oxime (compound A). 3. **Second reaction with P₂O₅ and heating**: The next step involves treating the oxime (compound A) with phosphorus pentoxide (P₂O₅) and heating it. P₂O₅ acts as a dehydrating agent, removing a water molecule from the oxime. The reaction can be represented as: \[ \text{CH}_3\text{C}=\text{N-OH} \xrightarrow{\text{P}_2\text{O}_5, \Delta} \text{CH}_3\text{C} \equiv \text{N} + \text{H}_2\text{O} \] The product formed is CH₃C≡N, which is called propionitrile (compound B). 4. **Final product**: Therefore, the final product B is CH₃C≡N (propionitrile). ### Summary of the Steps: - Step 1: Start with CH₃CHO (acetaldehyde). - Step 2: React with NH₂OH to form CH₃C=N-OH (acetaldehyde oxime). - Step 3: Treat with P₂O₅ and heat to remove water and form CH₃C≡N (propionitrile). ### Final Answer: The compound B formed in the reaction sequence is CH₃C≡N (propionitrile).
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