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An organic compound containes C=74.0%, H...

An organic compound containes `C=74.0%, H=8.65%` and `N=17.3%`. Its empirical formul ais

A

`C_5H_8N`

B

`C_(10)H_(12)N`

C

`C_5H_7N`

D

`C_(10)H_(14)N`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the empirical formula of the organic compound based on its percentage composition of carbon (C), hydrogen (H), and nitrogen (N), we follow these steps: ### Step 1: Convert percentages to grams Assume we have 100 g of the compound. This means: - Carbon (C) = 74.0 g - Hydrogen (H) = 8.65 g - Nitrogen (N) = 17.3 g ### Step 2: Convert grams to moles Next, we convert the mass of each element to moles using their respective molar masses: - Molar mass of Carbon (C) = 12 g/mol - Molar mass of Hydrogen (H) = 1 g/mol - Molar mass of Nitrogen (N) = 14 g/mol Calculating the number of moles for each element: - Moles of Carbon (C) = \( \frac{74.0 \, \text{g}}{12 \, \text{g/mol}} \) = 6.17 moles - Moles of Hydrogen (H) = \( \frac{8.65 \, \text{g}}{1 \, \text{g/mol}} \) = 8.65 moles - Moles of Nitrogen (N) = \( \frac{17.3 \, \text{g}}{14 \, \text{g/mol}} \) = 1.23 moles ### Step 3: Find the simplest mole ratio To find the simplest ratio, we divide the number of moles of each element by the smallest number of moles calculated: - The smallest number of moles is for Nitrogen (N) = 1.23 moles. Calculating the ratios: - Ratio of Carbon (C) = \( \frac{6.17}{1.23} \) ≈ 5.02 ≈ 5 - Ratio of Hydrogen (H) = \( \frac{8.65}{1.23} \) ≈ 7.03 ≈ 7 - Ratio of Nitrogen (N) = \( \frac{1.23}{1.23} \) = 1 ### Step 4: Write the empirical formula Now that we have the simplest whole number ratios, we can write the empirical formula: - Empirical formula = \( C_5H_7N_1 \) or simply \( C_5H_7N \) ### Conclusion The empirical formula of the organic compound is \( C_5H_7N \).
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