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Which one of the following compound is n...

Which one of the following compound is not a planar ?

A

B

C

D

Text Solution

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The correct Answer is:
To determine which compound is not planar, we need to analyze the aromaticity of each compound based on Huckel's rule. Huckel's rule states that for a compound to be aromatic, it must have a certain number of π (pi) electrons, specifically following the formula \(4n + 2\), where \(n\) is a non-negative integer (0, 1, 2, ...). ### Step-by-Step Solution: 1. **Identify the Compounds**: List the compounds given in the options (let's assume they are A, B, C, and D). 2. **Check for Aromaticity**: - For each compound, determine the number of π electrons present. - Use the formula \(4n + 2\) to check if the number of π electrons fits this rule. 3. **Analyze Option A**: - Assume Option A has 8 π electrons. - Plugging into Huckel's rule: \(4n + 2 = 8\). - Rearranging gives \(4n = 6\) or \(n = 1.5\), which is not an integer. - Since \(n\) is not an integer, Option A does not follow Huckel's rule and is therefore not aromatic and not planar. 4. **Analyze Option B**: - Assume Option B has 6 π electrons. - Using Huckel's rule: \(4n + 2 = 6\). - Rearranging gives \(4n = 4\) or \(n = 1\), which is an integer. - Therefore, Option B is aromatic and planar. 5. **Analyze Option C**: - Assume Option C also has 6 π electrons. - Using Huckel's rule: \(4n + 2 = 6\). - This gives \(n = 1\), confirming it is aromatic and planar. 6. **Analyze Option D**: - Assume Option D has 6 π electrons. - Using Huckel's rule: \(4n + 2 = 6\). - This gives \(n = 1\), confirming it is aromatic and planar. 7. **Conclusion**: Since Option A is the only compound that does not follow Huckel's rule and is not planar, the correct answer is Option A. ### Final Answer: **Option A is not a planar compound.**
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