Home
Class 12
CHEMISTRY
Consider the following reaction (A)overs...

Consider the following reaction `(A)overset((i)O_3)underset((ii)H_2"O"//Zn)rarrCH_3-overset(O)overset(||)C-CH_2-overset(O)overset(||)C-CH_2-overset(O)overset(||)C-CH_3+3HCHO` Compound 'A' will be

A

`CH_3-overset(O)overset(||)C-CH_2-overset(O)overset(||)C-CH_2-overset(CH_2)overset(||)C-CH_3`

B

`CH_3-overset(O)overset(||)C-CH_2-overset(CH_2)overset(||)C-CH_2-overset(O)overset(||)C-CH_3`

C

`CH_3-overset(CH_2)overset(||)C-CH_2-overset(CH_2)overset(||)C-CH_2-underset(CH_3)underset(|)C=CH_2`

D

All of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine the compound 'A' in the given reaction, we need to analyze the process of reductive ozonolysis and how it affects alkenes. Here’s a step-by-step breakdown of the solution: ### Step-by-Step Solution: 1. **Understanding Reductive Ozonolysis**: - Reductive ozonolysis involves the reaction of an alkene with ozone (O₃) followed by reduction (usually with zinc and water). This reaction cleaves the double bond of the alkene and forms carbonyl compounds (aldehydes and/or ketones). 2. **Analyzing the Products**: - The reaction produces a ketone and 3 moles of formaldehyde (HCHO). The presence of 3 moles of formaldehyde indicates that the original compound must have 3 terminal methylene groups (–CH₂–) adjacent to the double bonds. 3. **Identifying the Structure of Compound 'A'**: - Since we have 3 moles of formaldehyde formed, it suggests that the original compound 'A' must be a symmetrical alkene with three double bonds that can yield formaldehyde upon ozonolysis. - The structure of compound 'A' can be inferred to be an alkene with the following structure: \[ CH_3-CH=CH-CH_2-CH=CH-CH_2-CH=CH-CH_3 \] - This structure has three double bonds, and when ozonolysis occurs, it will yield three formaldehyde molecules and one ketone. 4. **Performing the Ozonolysis**: - When ozonolysis occurs on this compound, the double bonds will break, leading to the formation of three formaldehyde molecules and a ketone. The ketone will have the structure: \[ CH_3-C(=O)-CH_2-C(=O)-CH_2-C(=O)-CH_3 \] - This confirms that the original compound 'A' is indeed the alkene with three double bonds. 5. **Conclusion**: - Therefore, compound 'A' is the symmetrical alkene that upon ozonolysis produces the specified ketone and three moles of formaldehyde. ### Final Answer: Compound 'A' is: \[ CH_3-CH=CH-CH_2-CH=CH-CH_2-CH=CH-CH_3 \]
Promotional Banner

Similar Questions

Explore conceptually related problems

CH_3-overset(OH)overset(|)(CH)-overset(O)overset(||)(C )-CH_2 - CH_(3) will respond to

The IUPAC name of CH_(3)-overset(O)overset(||)(C)-CH_(2)-overset(OH)overset(|)(CH)-CHO is

Consider the following reaction CH_3-underset((A))(CH_2)-O-H+CH_3-underset((B))overset(O)overset(||)C-OHrarrCH_3-overset(O)overset(||)C-O-CH_2-CH_3+HOH In the above reaction ester formation takes place by

The order of stability of the following tautomeric compounds is (i). CH_(2)=overset(OH)overset(|)(CH)-CH_(2)-overset(O)overset(||)(C)-CH_(3)hArr (ii). CH_(3)-overset(O)overset(||)(C)-CH_(2)-overset(O)overset(||)(C)-CH_(3)hArr (iii). CH_(3)-overset(OH)overset(|)(C)=CH-overset(O)overset(||)(C)-CH_(3)

The order of stability of the following tautomeric compounds is (i). CH_(2)=overset(OH)overset(|)(CH)-CH_(2)-overset(O)overset(||)(C)-CH_(3)hArr (ii). CH_(3)-overset(O)overset(||)(C)-CH_(2)-overset(O)overset(||)(C)-CH_(3)hArr (iii). CH_(3)-overset(OH)overset(|)(C)=CH-overset(O)overset(||)(C)-CH_(3)

The following carbocation rearranges to CH_(2)=underset(CH_(3))underset(|)C-overset(CH_(3))overset(|)C-overset(o+)CH-overset(CH_(3))overset(|)(CH)-CH_(3)

The IUPAC name for CH_(3)-overset(O)overset(||)(C)-CH_(2)-CH_(2)-overset(O)overset(||)(C)-OH is ______.