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The reagent with which both acetaldehyde...

The reagent with which both acetaldehyde and acetophenone react easily are

A

Fehling's solution

B

Schiff's reagent

C

Tollen's reagent

D

2, 4 - dinitrophenylhydrazine

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the reagent that can react with both acetaldehyde and acetophenone. Let's analyze the options step by step. ### Step 1: Identify the Compounds - **Acetaldehyde (CH3CHO)**: This is an aldehyde. - **Acetophenone (C6H5COCH3)**: This is a ketone. ### Step 2: Understand the Reactivity of Aldehydes and Ketones - Aldehydes (like acetaldehyde) are generally more reactive than ketones (like acetophenone) when it comes to oxidation reactions. - Aldehydes can be oxidized to carboxylic acids, while ketones are more resistant to oxidation. ### Step 3: Analyze the Given Reagents 1. **Felling's Solution**: This is a weak oxidizing agent that reacts with aldehydes to form a red precipitate of cuprous oxide (Cu2O). It does not react with ketones. 2. **Sieve Reagent**: This reagent (para-rosaniline hydrochloride) can react with aldehydes to restore its pink color but does not react with ketones. 3. **Toluene Reagent**: This is not a standard reagent for either aldehydes or ketones. 4. **2,4-Dinitrophenylhydrazine (DNPH)**: This reagent reacts with both aldehydes and ketones to form hydrazones. ### Step 4: Determine the Correct Reagent Since we need a reagent that can react with both acetaldehyde and acetophenone: - **Felling's Solution**: Reacts only with acetaldehyde. - **Sieve Reagent**: Reacts only with acetaldehyde. - **Toluene Reagent**: No significant reaction with either. - **2,4-Dinitrophenylhydrazine**: Reacts with both acetaldehyde and acetophenone. ### Conclusion The correct answer is **2,4-Dinitrophenylhydrazine**, as it is the only reagent that reacts with both acetaldehyde and acetophenone. ### Final Answer The reagent with which both acetaldehyde and acetophenone react easily is **2,4-Dinitrophenylhydrazine**. ---
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