Home
Class 12
CHEMISTRY
What is (Z) is the following sequence of...

What is (Z) is the following sequence of reaction?
`HC-=CH overset((i)2NaNH_(2)(ii) 2CH_(3)I)rarr (X) overset(HgSO_(4),H_(2)SO_(4))rarr(Y) overset((i)NaOH+Br_(3)(ii)H_(3O^(+)))rarr (Z)`

A

`CH_(3)CH_(2)CH_(2)CHO`

B

`CH_(3)CH_(2)COCH_(3)`

C

`CH_(3)CH_(2)COOH`

D

`CH_(3)CH_(2)CH_(2)COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the final product (Z) in the given sequence of reactions, we will break down the steps as follows: ### Step 1: Reaction of Acetylene with Sodium Amide and Methyl Iodide 1. **Starting Material**: Acetylene (HC≡CH) 2. **Reagents**: 2 moles of Sodium Amide (NaNH₂) and 2 moles of Methyl Iodide (CH₃I) 3. **Reaction**: Sodium amide is a strong base and will deprotonate the acetylene, removing both acidic hydrogen atoms. This forms disodium acetylene (Na₂C₂H₂). 4. **Substitution**: The disodium acetylene will then react with 2 moles of methyl iodide, leading to the substitution of the sodium ions with methyl groups. **Product (X)**: The product after this reaction will be 1,2-dimethylacetylene (CH₃C≡CCH₃). ### Step 2: Hydration of 1,2-Dimethylacetylene 1. **Reagents**: Mercury(II) sulfate (HgSO₄) and sulfuric acid (H₂SO₄) 2. **Reaction**: The addition of water (hydration) occurs across the triple bond of the alkyne, forming an enol intermediate. 3. **Tautomerization**: The enol will tautomerize to form a more stable keto form. **Product (Y)**: The product after this step will be 2-pentanone (CH₃C(=O)C₂H₅). ### Step 3: Haloform Reaction 1. **Reagents**: Bromine (Br₂) and Sodium Hydroxide (NaOH) 2. **Reaction**: The presence of a methyl ketone (2-pentanone) will undergo a haloform reaction. This involves the halogenation of the methyl group adjacent to the carbonyl, followed by hydrolysis. 3. **Final Step**: The addition of acid (H₃O⁺) will convert the resulting sodium salt into the corresponding carboxylic acid. **Product (Z)**: The final product after this reaction will be propanoic acid (CH₃CH₂COOH). ### Final Answer Thus, the final product (Z) is **Propanoic Acid (CH₃CH₂COOH)**. ---
Promotional Banner

Similar Questions

Explore conceptually related problems

The final product (Z) is the following sequence of reaction CH_3CH_2NH_2overset(HNO_2)rarr(X)overset(Socl_2)rarr(Y) " is " overset(NH_3)rarr(Z)

Identify the final product (Z) in the following sequence of reactions : Me_2C=O+HCNrarr(X) overset(H_3O^+)rarr(Y)overset(H_2SO_4)rarr

What is Z in the following sequence of reactions? Z overset(PCl_(3))toX overset(alc.KOH)to Y underset((ii)H_(2)O boil)overset((i)Conc.H_(2)SO_(4))toZ

The end product (B) in the following sequence of reactions is CH_(3)Cl overset(KCN)rarr A overset(H_(2)O //H^(+))rarr B

Consider the following sequence of reactions C_(2)H_(5)C -= CH overset(CH_(3)MgBr)rarr A underset((2)H_(2)O^(+))overset((1)HCHO) rarr B The product (B) is

overset((i) NaNH_(2), NH_(3)(ii)CH_(3)-Br)rarr (A) overset((H_(2)" Lindlar'scatalyst"))rarr B

Write the product of following reactions : (i) CH_(3)-C-=C-CH=CH_(2) overset(O_(3)//H_(2)O_(2))rarr , (ii) , overset(O_(3)//H_(2)O_(2))rarr

In the reaction CH_3-C-=C-Hoverset((i) NaNH_2//NH_3(l))rarr(A)overset(CH_3-CH_2-CH_2-Br)rarr(B) The product B is

overset(|HgSO_4//H_2 SO_4)rarr(A) overset (2 mol of MeMgBr//H_3 O^(oplus))rarr (B) . (B) is :

In the following sequence of reaction, the product C is CH_(3)-Br overset(KCN) rarr A overset(H_(2)O^(+))rarr B overset(LiAlH_(4))underset("Ether")rarr C