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When dilute H(2)SO(4) and H(2)O(2) are a...

When dilute `H_(2)SO_(4) and H_(2)O_(2)` are added to a solution of chromate ions, an intense blue colour is produced, which is stable in ether. Theis is due to the formation of

A

`Cr_(2)O_(7)^(2-)`

B

`Cr_(2)O_(3)`

C

`CrO_(5)`

D

`CrO_(3)`

Text Solution

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The correct Answer is:
To solve the question regarding the intense blue color produced when dilute \( H_2SO_4 \) and \( H_2O_2 \) are added to a solution of chromate ions, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants in this reaction are chromate ions (\( CrO_4^{2-} \)), dilute sulfuric acid (\( H_2SO_4 \)), and hydrogen peroxide (\( H_2O_2 \)). 2. **Understand the Reaction**: - When chromate ions are treated with dilute \( H_2SO_4 \), the \( H^+ \) ions from the acid can interact with the chromate ions. - The presence of \( H_2O_2 \) introduces an oxidizing agent that can further react with the chromate ions. 3. **Write the Chemical Equation**: - The reaction can be represented as follows: \[ CrO_4^{2-} + 2 H^+ + 2 H_2O_2 \rightarrow CrO_5 + 3 H_2O \] - Here, \( CrO_5 \) is formed, which is a peroxo compound of chromium. 4. **Identify the Product**: - The product \( CrO_5 \) is known to produce an intense blue color when formed in solution. 5. **Stability in Ether**: - The intense blue color of \( CrO_5 \) is stable in ether, which is a non-polar solvent. This stability is important for the identification of the compound. 6. **Conclusion**: - Therefore, the intense blue color observed in the solution is due to the formation of \( CrO_5 \). ### Final Answer: The intense blue color produced is due to the formation of \( CrO_5 \).
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