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When a transition of electron in He^(+) ...

When a transition of electron in `He^(+)` takes place from `n_(2)" to "n_(1)` then wave number in terms of Rydberg constant R will be
`("Given "n_(1)+n_(2)=4, n_(2)-n_(1)=2)`

A

`(3R)/(4)`

B

`(8R)/(9)`

C

`(32R)/(9)`

D

(24R)/(9)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the wave number for the transition of an electron in \( He^+ \) from \( n_2 \) to \( n_1 \), we can follow these steps: ### Step 1: Determine the values of \( n_1 \) and \( n_2 \) We are given two equations: 1. \( n_1 + n_2 = 4 \) 2. \( n_2 - n_1 = 2 \) From the first equation, we can express \( n_1 \) in terms of \( n_2 \): \[ n_1 = 4 - n_2 \] Now, substituting this expression into the second equation: \[ n_2 - (4 - n_2) = 2 \] Simplifying this gives: \[ n_2 - 4 + n_2 = 2 \\ 2n_2 - 4 = 2 \\ 2n_2 = 6 \\ n_2 = 3 \] Now substituting \( n_2 \) back into the equation for \( n_1 \): \[ n_1 = 4 - n_2 = 4 - 3 = 1 \] ### Step 2: Use the Rydberg formula to find the wave number The wave number \( \bar{\nu} \) (in terms of Rydberg constant \( R \)) for the transition can be calculated using the Rydberg formula: \[ \bar{\nu} = RZ^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] For \( He^+ \), the atomic number \( Z \) is 2. Substituting \( n_1 = 1 \) and \( n_2 = 3 \): \[ \bar{\nu} = R \cdot 2^2 \left( \frac{1}{1^2} - \frac{1}{3^2} \right) \] Calculating further: \[ \bar{\nu} = R \cdot 4 \left( 1 - \frac{1}{9} \right) \\ = R \cdot 4 \left( \frac{9 - 1}{9} \right) \\ = R \cdot 4 \left( \frac{8}{9} \right) \\ = \frac{32R}{9} \] ### Conclusion The wave number for the transition from \( n_2 \) to \( n_1 \) in \( He^+ \) is: \[ \bar{\nu} = \frac{32R}{9} \]
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