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The silicate anion in the mineral kinoit...

The silicate anion in the mineral kinoite is a chain of three `SiO_(4)` tetrahedra, that share corners with adjacent tetrahedra. The charge pof silicate anion is

A

`-4`

B

`-8`

C

`-6`

D

`-2`

Text Solution

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The correct Answer is:
To determine the charge of the silicate anion in the mineral kinoite, we need to analyze the structure of the silicate anion formed by three SiO₄ tetrahedra. ### Step-by-Step Solution: 1. **Understanding the Tetrahedra Structure**: Each SiO₄ tetrahedron consists of one silicon atom (Si) surrounded by four oxygen atoms (O). The silicon atom has a +4 charge, while each oxygen atom has a -2 charge. 2. **Calculating the Charge of One Tetrahedron**: - Charge from silicon: +4 - Charge from four oxygen atoms: 4 × (-2) = -8 - Total charge of one SiO₄ tetrahedron = +4 + (-8) = -4 3. **Analyzing the Chain of Tetrahedra**: In the case of kinoite, there are three SiO₄ tetrahedra linked together in a chain. When tetrahedra share corners, they do not contribute additional negative charges from the shared oxygen atoms. 4. **Calculating the Total Charge for Three Tetrahedra**: - Total charge from three tetrahedra = 3 × (-4) = -12 5. **Considering Shared Oxygen Atoms**: When three tetrahedra are linked, some oxygen atoms are shared. In this case, we need to determine how many oxygen atoms are effectively contributing to the total charge. - Each tetrahedron shares oxygen atoms with adjacent tetrahedra. In a chain of three tetrahedra, there are 2 shared oxygen atoms (one between the first and second tetrahedra, and another between the second and third). - Therefore, the total number of unique oxygen atoms = 12 (from three tetrahedra) - 2 (shared) = 10. 6. **Final Charge Calculation**: - Total charge from silicon: 3 × (+4) = +12 - Total charge from oxygen: 10 × (-2) = -20 - Overall charge of the silicate anion = +12 + (-20) = -8 7. **Conclusion**: The charge of the silicate anion in kinoite is -8. ### Final Answer: The charge of the silicate anion is -8.
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