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The first orbital of H is represented by...

The first orbital of H is represented by: `psi=(1)/(sqrtpi)((1)/(a_(0)))^(3//2)e^(-r//a_(0))`, where `a_(0)` is Bohr's radius. The probability of finding the electron at a distance r, from the nucleus in the region dV is :

A

`psi^(2)dr`

B

`int psi^(2)4pir^(2)dv`

C

`psi^(2)4pir^(2)dr`

D

`int psidv`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to find the probability of finding an electron at a distance \( r \) from the nucleus in the hydrogen atom, given the wave function \( \psi \). ### Step-by-Step Solution: 1. **Identify the Wave Function**: The wave function for the first orbital of hydrogen is given as: \[ \psi = \frac{1}{\sqrt{\pi}} \left(\frac{1}{a_0}\right)^{3/2} e^{-r/a_0} \] where \( a_0 \) is the Bohr radius. 2. **Calculate \( \psi^2 \)**: The probability density is given by the square of the wave function: \[ \psi^2 = \left(\frac{1}{\sqrt{\pi}} \left(\frac{1}{a_0}\right)^{3/2} e^{-r/a_0}\right)^2 = \frac{1}{\pi} \left(\frac{1}{a_0}\right)^3 e^{-2r/a_0} \] 3. **Set Up the Probability Element**: The probability of finding the electron in a spherical shell of thickness \( dr \) at a distance \( r \) from the nucleus is given by: \[ dP = \psi^2 \cdot dV \] where \( dV \) is the volume element in spherical coordinates: \[ dV = 4\pi r^2 dr \] Therefore, \[ dP = \psi^2 \cdot 4\pi r^2 dr \] 4. **Substitute \( \psi^2 \) into the Probability Element**: Substitute \( \psi^2 \) into the equation for \( dP \): \[ dP = \left(\frac{1}{\pi} \left(\frac{1}{a_0}\right)^3 e^{-2r/a_0}\right) \cdot 4\pi r^2 dr \] 5. **Simplify the Expression**: Simplifying the expression gives: \[ dP = \frac{4}{a_0^3} e^{-2r/a_0} r^2 dr \] 6. **Conclusion**: The probability of finding the electron at a distance \( r \) from the nucleus in the region \( dV \) is: \[ dP = \frac{4}{a_0^3} e^{-2r/a_0} r^2 dr \] ### Final Answer: The probability of finding the electron at a distance \( r \) from the nucleus in the region \( dV \) is: \[ dP = \frac{4}{a_0^3} e^{-2r/a_0} r^2 dr \]
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