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The reaction sequence C(6)H(5)-CH=CH-C...

The reaction sequence
`C_(6)H_(5)-CH=CH-CHOoverset([X])rarr C_(6)H_(5)-CH_(2)-CH_(2)-CH_(2)OH`
[X] will be

A

`LiAlH_(4)`

B

`NaBH_(4)`

C

Aluminium isopropoxide

D

All of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the reagent [X] that can convert the unsaturated aldehyde (cinnamaldehyde) to the corresponding saturated alcohol. The reaction sequence is as follows: **Step 1: Identify the starting material and the product.** - Starting material: C₆H₅-CH=CH-CHO (cinnamaldehyde) - Product: C₆H₅-CH₂-CH₂-CH₂OH (a primary alcohol) **Step 2: Analyze the functional groups.** - The starting material contains an aldehyde group (-CHO) and a double bond (C=CH). - The product is a primary alcohol (-CH₂OH) with no double bonds. **Step 3: Determine the type of reaction required.** - We need to reduce both the double bond (C=CH) and the aldehyde group (CHO) to achieve the final product. **Step 4: Identify suitable reducing agents.** - Lithium aluminum hydride (LiAlH₄) is a strong reducing agent that can reduce both aldehydes and alkenes. - Sodium borohydride (NaBH₄) is a milder reducing agent that can reduce aldehydes but not alkenes. - Aluminum isopropoxide is not typically used as a reducing agent for these types of reactions. **Step 5: Conclude the best reagent.** - Since we need to reduce both the double bond and the aldehyde group, the best choice for [X] is lithium aluminum hydride (LiAlH₄). Thus, the answer is: **[X] = Lithium aluminum hydride (LiAlH₄)**
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