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In the given reaction sequence C(6)H(5...

In the given reaction sequence
`C_(6)H_(5)CHO+CH_(3)-NO_(2)overset((i)NaOH(ii)Delta)rarr[X]`
[X] will be

A

`C_(6)H_(5)-CHOH-CH_(2)-CHO`

B

`C_(6)H_(5)CH_(2)OH`

C

`C_(6)H_(5)-COOH`

D

`C_(6)H_(5)-CH=CH-NO_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reaction between benzaldehyde (C₆H₅CHO) and nitromethane (CH₃NO₂) in the presence of sodium hydroxide (NaOH) and heat. ### Step-by-Step Solution: 1. **Identify the Reactants**: - We have benzaldehyde (C₆H₅CHO) and nitromethane (CH₃NO₂). 2. **Understand the Role of Sodium Hydroxide**: - Sodium hydroxide acts as a base in this reaction. It will deprotonate the nitromethane, which has an acidic hydrogen on the carbon adjacent to the nitro group. 3. **Deprotonation of Nitromethane**: - The hydroxide ion (OH⁻) from NaOH abstracts the acidic hydrogen from nitromethane (CH₃NO₂), forming a nitronate ion (CH₂NO₂⁻). 4. **Nucleophilic Addition**: - The nitronate ion (CH₂NO₂⁻) acts as a nucleophile and attacks the carbonyl carbon of benzaldehyde (C₆H₅CHO). This results in the formation of a new intermediate. 5. **Formation of the Intermediate**: - The intermediate formed can be represented as C₆H₅C(OH)(CH₂NO₂). This intermediate has a hydroxyl group (OH) and the nitro group (NO₂) attached to the same carbon. 6. **Protonation**: - The intermediate can then undergo protonation to form a more stable compound, which is C₆H₅C(CH₂NO₂)(OH). 7. **Heating and Elimination of Water**: - Upon heating, this compound can undergo dehydration (loss of water) to form an α,β-unsaturated carbonyl compound. The final product will be C₆H₅C=CHNO₂. 8. **Final Product**: - The final product [X] is thus C₆H₅C=CHNO₂, which is the compound formed after the aldol condensation-like reaction and subsequent dehydration. ### Conclusion: The product [X] formed in the reaction sequence is C₆H₅C=CHNO₂.
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