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The IUPAC name of the given structure CH...

The IUPAC name of the given structure `CH_(3)-overset(O)overset(||)C-overset(Br)overset(|)CH-underset(I)underset(|)CH-COOH` is-

A

4 - keto -3- bromo -2- iodopentanoic acid

B

2 - iodo -3- bromo -4- keto - pentanoic acid

C

3 - bromo -2- iodo -4- ketopentanoic acid

D

4 - carboxy -3- bromo -4- iodopentanoic acid

Text Solution

AI Generated Solution

The correct Answer is:
To derive the IUPAC name of the given structure `CH3-CO-C(Br)-C(I)-CH-COOH`, we will follow these steps: ### Step 1: Identify the main functional group The main functional group in the structure is the carboxylic acid group (-COOH). According to IUPAC nomenclature, carboxylic acids take precedence over other functional groups. ### Step 2: Determine the longest carbon chain Count the number of carbon atoms in the longest continuous chain that includes the carboxylic acid group. In this case, there are 5 carbon atoms in total. ### Step 3: Number the carbon chain Number the carbon chain starting from the end nearest to the carboxylic acid group. This gives the following numbering: - Carbon 1: COOH (carboxylic acid) - Carbon 2: Iodine substituent (I) - Carbon 3: Bromo substituent (Br) - Carbon 4: Ketone group (C=O) - Carbon 5: Methyl group (CH3) ### Step 4: Identify substituents and their positions - At Carbon 2, there is an iodine atom (Iodo). - At Carbon 3, there is a bromine atom (Bromo). - At Carbon 4, there is a ketone group (Keto). ### Step 5: Assemble the name According to IUPAC rules, substituents are listed in alphabetical order regardless of their position numbers. Therefore, we will list the substituents as follows: - Bromo (from Carbon 3) - Iodo (from Carbon 2) - Keto (from Carbon 4) ### Step 6: Combine substituents with the main chain name The base name for a 5-carbon chain is "pentane." Since the main functional group is a carboxylic acid, we will use the suffix "-oic acid." Thus, the base name becomes "pentanoic acid." ### Step 7: Finalize the IUPAC name Putting it all together, the full IUPAC name is: **3-Bromo-2-Iodo-4-ketopentanoic acid** ### Final Answer The IUPAC name of the given structure is **3-Bromo-2-Iodo-4-ketopentanoic acid**.
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The IUPAC name of CH_(3)-overset(COOH)overset(|)(C )H-CH_(2)-overset(COOH)overset(|)(C)H-overset(CH_(3))overset(|)(CH)-COOH is :-

The IUPAC name of following structure is CH_(3) - overset(CH_(3)) overset(|)(CH)-underset(O)underset(||)C-CH_(2)-CH_(2)OH

Knowledge Check

  • The IUPAC name of -overset(O)overset(||)C- underset(C_2 H_5) underset(|) CH -underset(CH_3)underset(|)CH-CH_3 is

    A
    3-(Methylethyl) pentan-2-one
    B
    3-(Methylethyl)pentan-4-one
    C
    3-Ethyl-4-methylpentan-2-one
    D
    3-Ethyl-2-methylpentan-4-one
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