Home
Class 12
CHEMISTRY
Each of the compounmds Pt(NH(3))(6)Cl(4)...

Each of the compounmds `Pt(NH_(3))_(6)Cl_(4), Cr(NH_(3))_(6)Cl_(3) and K_(2)PtCl_(6)Co(NH_(3))_(4)Cl_(3)` were dissolved in water to make its 0.01 M solution. The correct order of their increasing conductivity in solution is

A

`K_(2){T Cl_(6) lt Co(NH_(3))_(4).l_(3) lt Cr(NH_(3))_(6)Cl_(3) lt Pt (NH_(3))_(6)Cl_(4)`

B

`Cr(NH_(3))_(6)Clk_(3) lt Co(NH_(3))_(4).Cl_(3) lt K_(2)PtCl_(6) lt Pt (NH_(3))_(6)Cl_(4)`

C

`Co(NH_(3))_(4).Cl_(3)lt K_(2)PtCl_(6) lt Cr(NH_(3))_(6)Cl_(3) lt Pt (NH_(3))_(6)Cl_(4)`

D

`Pt(NH_(3))_(6)Cl_(4) lt Co(NH_(3))_(6).Cl_(3) lt Cr(NH_(3))_(6) Cl_(3)lt K_(2)PtCl_(6)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of increasing conductivity for the given compounds when dissolved in water, we need to analyze the number of ions produced by each compound in solution. Conductivity is directly related to the number of ions present; more ions result in higher conductivity. ### Step-by-Step Solution: 1. **Identify the Compounds:** - Pt(NH₃)₆Cl₄ - Cr(NH₃)₆Cl₃ - K₂PtCl₆ - Co(NH₃)₄Cl₃ 2. **Determine the Number of Ions Produced by Each Compound:** - For **Pt(NH₃)₆Cl₄**: - 1 Pt ion + 6 NH₃ (neutral, does not contribute to conductivity) + 4 Cl⁻ ions - Total ions = 1 + 0 + 4 = **5 ions** - For **Cr(NH₃)₆Cl₃**: - 1 Cr ion + 6 NH₃ (neutral) + 3 Cl⁻ ions - Total ions = 1 + 0 + 3 = **4 ions** - For **K₂PtCl₆**: - 2 K⁺ ions + 1 Pt ion + 6 Cl⁻ ions - Total ions = 2 + 1 + 6 = **9 ions** - For **Co(NH₃)₄Cl₃**: - 1 Co ion + 4 NH₃ (neutral) + 3 Cl⁻ ions - Total ions = 1 + 0 + 3 = **4 ions** 3. **List the Compounds with Their Total Ion Counts:** - Pt(NH₃)₆Cl₄: 5 ions - Cr(NH₃)₆Cl₃: 4 ions - K₂PtCl₆: 9 ions - Co(NH₃)₄Cl₃: 4 ions 4. **Rank the Compounds by Number of Ions:** - Cr(NH₃)₆Cl₃: 4 ions (lowest conductivity) - Co(NH₃)₄Cl₃: 4 ions (same as above, but will be considered next) - Pt(NH₃)₆Cl₄: 5 ions - K₂PtCl₆: 9 ions (highest conductivity) 5. **Final Order of Increasing Conductivity:** - Cr(NH₃)₆Cl₃ < Co(NH₃)₄Cl₃ < Pt(NH₃)₆Cl₄ < K₂PtCl₆ ### Conclusion: The correct order of increasing conductivity in the solution is: **Cr(NH₃)₆Cl₃ < Co(NH₃)₄Cl₃ < Pt(NH₃)₆Cl₄ < K₂PtCl₆**
Promotional Banner

Similar Questions

Explore conceptually related problems

Each of these compounds Pt(NH_(3))_(6)Cl_(4), Cr(NH_(3))_(6)Cl_(3), Co(NH_(3))_(4)Cl_(3) and K_(2)PtI_(6) has been dissolved in water to make its 0,001 M solution. Rank them in order of their increasing conductivity.

The name of the complex [Pt(NH_3)_6]Cl_4 is

[Pt(NH_(3))_(4)][CuCl_(4)] and [Cu(NH_(3))_(4)][PtCl_(4)] are known as

[Co(NH_(3))_(5)NO_(2)]Cl_(2) and [Co(NH_(3))_(5)ONO]Cl_(2) are related to each other as :-

In solution, the complex, [Pt(NH_3)_6]Cl_4 gives

The correct name of |Pt(NH_(3))_(4)Cl_(2)||PtCl_(4)| is

[Cr(NH_(3))_(6)]^(3+)+6HCl to Cr^(3+)(aq)+6NH_(4)Cl

The correct IUPAC name of [Pt(NH_(3))_(2)Cl_(4)] is

The oxidation states of Cr in [Cr(H_(2)O)_(6)]Cl_(3). ,[Cr(C_(6)H_(6))_(2)] and K_(2)[Cr(CN)_(2)(O)_2(O_2)(NH_(3))] respectively are

Two complexes [Cr(H_(2)O_(6))_(6)]Cl_(3) and [Cr(NH_(3))_(6)]Cl_(3) (B) are violet and yellow coloured, respectively. The incorrect statement regarding them is :