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In Mayer's relation: C(P)-C(V)=R 'R'...

In Mayer's relation:
`C_(P)-C_(V)=R`
'R' stands for:

A

translational kinetic energy of 1 mol gas

B

rotational kinetic energy of 1 mol gas

C

vibrational kinetic energy of 1 mol gas

D

work done to increase the temperature of 1 mol gas by one degree

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding Mayer's relation \( C_{P} - C_{V} = R \), we need to analyze what \( R \) represents in this context. Here's a step-by-step breakdown of the solution: ### Step 1: Understand Mayer's Relation Mayer's relation states that the difference between the heat capacities at constant pressure (\( C_{P} \)) and constant volume (\( C_{V} \)) for an ideal gas is equal to the gas constant \( R \): \[ C_{P} - C_{V} = R \] ### Step 2: Identify the Variables In this relation: - \( C_{P} \) is the molar heat capacity at constant pressure. - \( C_{V} \) is the molar heat capacity at constant volume. - \( R \) is the universal gas constant. ### Step 3: Consider the Ideal Gas Law The ideal gas law is given by: \[ PV = nRT \] For one mole of gas (\( n = 1 \)), this simplifies to: \[ PV = RT \] ### Step 4: Analyze Changes in Volume and Temperature Now, consider a small change in volume (\( \Delta V \)) and an increase in temperature by 1 degree Celsius. The new state can be expressed as: \[ PV + P\Delta V = R(T + 1) \] ### Step 5: Substitute and Rearrange Substituting \( PV = RT \) into the equation gives: \[ RT + P\Delta V = RT + R \] By rearranging, we find: \[ P\Delta V = R \] ### Step 6: Relate Work Done to \( R \) The work done (\( W \)) during this process can be expressed as: \[ W = P\Delta V \] From our previous step, we see that: \[ W = R \] ### Conclusion Thus, we conclude that \( R \) represents the work done to increase the temperature of one mole of gas by 1 degree Celsius. ### Final Answer In Mayer's relation, \( R \) stands for the work done to increase the temperature of 1 mole of gas by 1 degree Celsius. ---
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