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Products of the reaction which is given ...

Products of the reaction which is given below will be
`CH_(3)-underset(CH_(3))underset("| ")"C "=CH-CH_(3)overset((i)OsO_(4)(ii)aq. NaHSO_(3))underset((iii)NaIO_(4))rarr`

A

Vic diol

B

Vic dicarbonyl compound

C

`CH_(3)-overset(O)overset(||)C-CH_(3) and CH_(3)-CHO`

D

`CH_(3)-overset(O)overset(||)C-CH_(3) and CH_(3)-COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the products of the given reaction, we will analyze the reaction step by step. ### Step 1: Identify the Starting Compound The starting compound is 2,3-dimethyl-2-butene, which has the structure: ``` CH3 | CH3 - C = CH - CH3 ``` ### Step 2: Understand the Reagents The reagents used in the reaction are: 1. **OsO4 (Osmium Tetroxide)** - This reagent is used for the syn-dihydroxylation of alkenes, adding two hydroxyl groups across the double bond. 2. **NaHSO3 (Sodium Bisulfite)** - This is used to quench the reaction and help in the isolation of the diol formed. 3. **NaIO4 (Sodium Periodate)** - This reagent cleaves the diol formed into carbonyl compounds (aldehydes and ketones). ### Step 3: Reaction Mechanism 1. **Dihydroxylation**: The alkene reacts with OsO4 to form a cyclic osmate ester, which upon hydrolysis with NaHSO3 leads to the formation of a vicinal diol (two hydroxyl groups on adjacent carbons). The product after this step will be: ``` OH | CH3 - C - CH - CH3 | OH ``` 2. **Cleavage with NaIO4**: The vicinal diol undergoes oxidative cleavage with sodium periodate, breaking the C-C bond between the two carbons that were originally part of the double bond. This will yield: - A ketone from the carbon chain on one side (acetone). - An aldehyde from the carbon chain on the other side (acetaldehyde). ### Step 4: Final Products The final products of the reaction will be: - **Acetone (2-propanone)**: CH3-CO-CH3 - **Acetaldehyde (ethanal)**: CH3-CHO ### Conclusion Thus, the products of the reaction are acetone and acetaldehyde.
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