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When the following aldohexose exists in ...

When the following aldohexose exists in Pyranose from, the total number of stereoisomers in its pyranose form is

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To determine the total number of stereoisomers for an aldohexose (specifically glucose) in its pyranose form, we can follow these steps: ### Step 1: Identify the Structure of Glucose Glucose is an aldohexose, meaning it contains an aldehyde group and six carbon atoms. In its pyranose form, glucose forms a six-membered ring structure. ### Step 2: Draw the Pyranose Form of Glucose The pyranose form of glucose is represented as a six-membered ring with five carbon atoms and one oxygen atom. The structure includes hydroxyl (OH) groups and hydrogen (H) atoms attached to the carbon atoms. ### Step 3: Identify Chiral Carbons A chiral carbon is a carbon atom that is attached to four different groups. In the pyranose form of glucose, we need to identify how many chiral carbons are present. - In the pyranose form of glucose, the chiral carbons are typically at positions 2, 3, 4, and 5. - The carbon at position 1 (the anomeric carbon) can also be considered chiral depending on whether it is in the alpha or beta form. ### Step 4: Count the Number of Chiral Carbons In the case of glucose in its pyranose form, we have: - Carbon 1 (anomeric carbon) - Carbon 2 - Carbon 3 - Carbon 4 - Carbon 5 Thus, there are a total of **5 chiral carbons**. ### Step 5: Calculate the Number of Stereoisomers The number of stereoisomers can be calculated using the formula: \[ \text{Number of stereoisomers} = 2^n \] where \( n \) is the number of chiral carbons. Substituting the value of \( n \): \[ \text{Number of stereoisomers} = 2^5 = 32 \] ### Conclusion The total number of stereoisomers for glucose in its pyranose form is **32**. ---
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