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In the reaction sequence CH(3)-CO-CH(3)o...

In the reaction sequence `CH_(3)-CO-CH_(3)overset(C_(2)H_(5)OH//OH^(-))rarr(A) overset(C_(2)H_(5)OH//H^(+))rarr[X]` will be

A

B

C

D

Text Solution

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The correct Answer is:
To solve the problem, we will go through the reaction sequence step by step: 1. **Identify the starting compound**: The starting compound is CH₃COCH₃, which is acetone (a ketone). 2. **First reaction with C₂H₅OH and OH⁻**: - In the presence of ethanol (C₂H₅OH) and hydroxide ion (OH⁻), the hydroxide ion will act as a nucleophile and attack the carbonyl carbon of acetone. - This results in the formation of a tetrahedral intermediate, which can be represented as: \[ CH₃C(OH)(C₂H₅)CH₃ \] - After the nucleophilic attack, the intermediate will rearrange to form a hemiketal: \[ A: CH₃C(OC₂H₅)(OH)CH₃ \] 3. **Second reaction with C₂H₅OH and H⁺**: - The hemiketal (A) formed in the first step will now react with ethanol in the presence of an acid (H⁺). - The protonation of the hydroxyl group (OH) will make it a better leaving group (water). - The ethanol will then attack the carbon that was previously part of the carbonyl group, leading to the formation of a ketal. - The final product (X) can be represented as: \[ X: CH₃C(OC₂H₅)₂CH₃ \] 4. **Conclusion**: The final product X is a ketal formed from the reaction of acetone with ethanol. ### Summary of the Reaction Sequence: - Starting compound: Acetone (CH₃COCH₃) - Intermediate A: Hemiketal (CH₃C(OC₂H₅)(OH)CH₃) - Final product X: Ketal (CH₃C(OC₂H₅)₂CH₃) ### Final Answer: The compound X is a ketal derived from acetone and ethanol. ---
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