Home
Class 12
CHEMISTRY
An unknown compound AC(8)H(10)O(3) on a...

An unknown compound `AC_(8)H_(10)O_(3)` on acetylation with `CH_(3)COCl//Py` forms acetyl derivative of A whose MW is 280. A on treat with `CH_(2)N_(2)` gives methyl etherof B having MW 182. If the number of phenolic hydroxyls and alcoholic hydroxyls in the compound A are X and Y respectively. Find the sum of `X+Y` here?,

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the information provided about the unknown compound \( A \) with the molecular formula \( C_8H_{10}O_3 \). ### Step 1: Calculate the Molecular Weight of Compound A The molecular formula of compound \( A \) is \( C_8H_{10}O_3 \). We can calculate its molecular weight as follows: \[ \text{Molecular Weight} = (12 \times 8) + (1 \times 10) + (16 \times 3) \] \[ = 96 + 10 + 48 = 154 \] **Hint:** Remember to multiply the number of each type of atom by its atomic weight and sum them up. ### Step 2: Determine the Increase in Molecular Weight After Acetylation When compound \( A \) undergoes acetylation with \( CH_3COCl \), it forms an acetyl derivative with a molecular weight of 280. The increase in molecular weight due to the acetylation can be calculated as: \[ \text{Increase in Molecular Weight} = 280 - 154 = 126 \] **Hint:** Subtract the original molecular weight from the new molecular weight to find the increase. ### Step 3: Calculate the Number of Acetyl Groups Introduced Each acetyl group contributes an increase of 42 units to the molecular weight (as calculated from the acetylation process). Therefore, the number of acetyl groups introduced can be calculated as: \[ \text{Number of Acetyl Groups} = \frac{126}{42} = 3 \] **Hint:** Divide the total increase in molecular weight by the increase per acetyl group to find how many groups were added. ### Step 4: Relate the Number of Hydroxyl Groups to the Acetyl Groups The acetylation can occur on both phenolic and alcoholic hydroxyl groups. Since we found that a total of 3 acetyl groups were introduced, we can conclude that the total number of hydroxyl groups (both phenolic and alcoholic) in compound \( A \) is also 3. Let \( X \) be the number of phenolic hydroxyls and \( Y \) be the number of alcoholic hydroxyls. Thus, we have: \[ X + Y = 3 \] **Hint:** The total number of hydroxyl groups that can be acetylated equals the number of acetyl groups introduced. ### Step 5: Conclusion The sum of \( X \) (phenolic hydroxyls) and \( Y \) (alcoholic hydroxyls) is: \[ X + Y = 3 \] Thus, the answer to the question is: \[ \boxed{3} \]
Promotional Banner

Similar Questions

Explore conceptually related problems

Unknown compound A C_9H_8O_5 on methylation with (CH_3)SO_4//NaOH forms methyl derivative whose MW is 210. The number of hydroxyl groups is A is

A compound 'X', molecular formula C_4H_8Br_2 on treatment with zinc in an alcoholic solution, forms an alkene Y. Compounds X and Y respectively are

An organic compound (A) (C_(6)H_(10)O) on reaction with CH_(3)MgBr followed by acid treatment gives compound (B). The compound (B) on ozonolysis gives compound (C ), which in the presence of a base gives 1-acetyl cyclopentene (D). The compound (B) on reaction with HBr gives compound (E ). Write the structures of (A), (B), (C ), (D), and (E ). Show how (D) is formed from (C ).

0.40 g of an organic compound (A), (M.F.-C_(5)H_(8)O) reacts with x mole of CH_(3)MgBr to liberate 224 mL of a gas at STP. With excess of H_(2) , (A) gives pentan-1-ol. The correct structure of (A) is :

A benzenoid organic compound A(C_(8)H_(8)O) gives B and white crystalline solid C with Cl_(2) and NaOH . On heating compound B gives a compound with unpleasant smell with CH_(3)-CH_(2)-NH_(2) and alcoholic KOH. Compound A is

A compound (X) of molecular formula C_(3)H_(6)O forms bisulphate complex, gives iodoform test but does not reduce Tollens reagent. (X) on reaction with CH_(3)MgBr//H_(3)O^(+) gives a compound (Y) that cannot

An acidic compound (A) (C_4 H_8 O_3) loses its optical activity on strong heating yielding (B) (C_4 H_6 O_2) which reacts readly with KMnO_4 . (B) forms a dervative ( C) with SOCl_2 which on reaction with (CH_3)_2 NH gives (D) . The compound (A) on oxidation with dilute chromic acid gives an unstable compound (E) which decarboxylates readily to give (F) (C_3 H_6 O) . The compound (F) gives a hydrocarbon (G) on treatment with amalgamated Zn and HCl . Give the structures of (A) to (G) with proper reasoning.

The compound X on treatment with acidified K_(2)Cr_(2)O_(7) gives compound Y which reacts with I_(2) and Na_(2)CO_(3) to form tri-iodomethane. The compound X is :

Compound (A) C_(7)H_(8)O is insoluble in aqueous NaHCO_(3) and dissolves in aqueous NaOH and gives a characteristic colour with neutral FeCl_(3) . When treated with Br_(2) (A) forms compound (B) C_(7)H_(5)O Br_(3) . The most probable structure of compound A is :

An organic compound [X]. C_(5)H_(8)O reacts with hydroxylamine to form [Y]. In the presence of conc. H_(2)SO_(4) gives delta -lactam. [X] neither give Benedicts test nor it respond positively towards haloform test. The compound [X] is