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Dehydration of alcohol into alkene by co...

Dehydration of alcohol into alkene by concentration `H_2SO_4` involves which among the following reaction intermediate ?

A

Free radical

B

Carbocation

C

Carbanion

D

Carbene

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the dehydration of alcohol into alkene by concentrated H₂SO₄ and the reaction intermediate involved, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Reaction**: The dehydration of alcohol involves the removal of a water molecule (H₂O) from the alcohol (RCH₂OH) to form an alkene (RCH=CH₂). This reaction is facilitated by concentrated sulfuric acid (H₂SO₄). 2. **Protonation of Alcohol**: The first step in the mechanism is the protonation of the alcohol. The lone pair of electrons on the oxygen atom of the alcohol (RCH₂OH) attacks a proton (H⁺) from the sulfuric acid. This forms an oxonium ion (RCH₂OH₂⁺). 3. **Formation of Carbocation**: The oxonium ion (RCH₂OH₂⁺) is unstable and undergoes a loss of water (H₂O) to form a carbocation (RCH₂⁺). This step is crucial as it generates the positively charged intermediate. 4. **Deprotonation to Form Alkene**: The carbocation (RCH₂⁺) can then lose a proton (H⁺) to form the alkene (RCH=CH₂). This step completes the dehydration process. 5. **Conclusion**: The reaction intermediate formed during the dehydration of alcohol by concentrated H₂SO₄ is a carbocation. ### Final Answer: The reaction intermediate involved in the dehydration of alcohol into alkene by concentrated H₂SO₄ is a **carbocation**.
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