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Ozone depletion takes place as : 2O(3)...

Ozone depletion takes place as :
`2O_(3)(g)rarr3O_(2)(g)`
Step1: `O_(3)(g)overset(k)hArrO_(2)(g)+O(g)" "`(fast)
Step2 : `O_(3)(g)+[O]overset(k)rarr2O_(2)(g)" "` (slow)
order of the reaction will be :

A

1

B

2

C

3

D

unpredictable

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of the reaction for the given ozone depletion process, we will analyze the provided steps and focus on the rate-determining step. ### Step-by-Step Solution: **Step 1: Identify the Rate-Determining Step** - The reaction consists of two steps: - Step 1 (Fast): \( O_3(g) \rightleftharpoons O_2(g) + O(g) \) - Step 2 (Slow): \( O_3(g) + [O] \rightarrow 2O_2(g) \) - The slow step is the rate-determining step, which means that the rate of the overall reaction is determined by this step. **Step 2: Write the Rate Law for the Slow Step** - For the slow step, the rate can be expressed as: \[ \text{Rate} = k [O_3][O] \] where \( k \) is the rate constant for the slow step. **Step 3: Identify the Intermediate** - In the slow step, \( [O] \) is an intermediate. It is produced in the fast step and consumed in the slow step. Since intermediates do not appear in the overall balanced equation, we need to eliminate \( [O] \) from our rate expression. **Step 4: Relate the Intermediate to the Reactants** - From the fast step, we can express \( [O] \) in terms of \( [O_3] \) and \( [O_2] \): \[ O_3 \rightleftharpoons O_2 + O \] This implies that: \[ [O] = \frac{[O_3] - [O_2]}{1} \] However, for simplicity in the rate law, we can assume that \( [O] \) is proportional to \( [O_3] \) since \( O_2 \) is also produced. **Step 5: Substitute the Intermediate into the Rate Law** - Substituting \( [O] \) back into the rate law: \[ \text{Rate} = k [O_3] \left( \frac{[O_3]}{K} \right) \] where \( K \) is the equilibrium constant for the fast step. **Step 6: Simplify the Rate Expression** - This gives us: \[ \text{Rate} = k' [O_3]^2 \] where \( k' = \frac{k}{K} \). **Step 7: Determine the Order of the Reaction** - The overall order of the reaction is determined by the sum of the powers of the concentration terms in the rate law. Here, the order is 2 (from \( [O_3]^2 \)). ### Conclusion - The order of the reaction is **2**.
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