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1-Penten-4-yne reacts with 1 mol bromine...

1-Penten-4-yne reacts with 1 mol bromine at -`80°C` to produce :

A

4,4,5,5-Tetrabromopentene

B

1,2-Dibromo-1,4-pentadiene

C

1,1,2,2,4,5-Hexabromopentane

D

4,5-dibromopentyne

Text Solution

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The correct Answer is:
To solve the problem of what product is formed when 1-Penten-4-yne reacts with 1 mole of bromine at -80°C, we can follow these steps: ### Step 1: Understand the Reactants 1-Penten-4-yne is an alkyne with a double bond (C=C) and a triple bond (C≡C) in its structure. The structure can be represented as follows: ``` CH2=CH-CH2-C≡C-H ``` ### Step 2: Reaction with Bromine When alkenes and alkynes react with bromine (Br2), they undergo an electrophilic addition reaction. At low temperatures (like -80°C), the reaction tends to proceed with less rearrangement and more selective addition. ### Step 3: Identify the Site of Reaction In 1-Penten-4-yne, the presence of both double and triple bonds means that bromine can add across these unsaturations. However, since we are using only 1 mole of bromine, we can expect the addition to occur at the double bond (C=C) first, leading to the formation of a dibromide. ### Step 4: Draw the Product When bromine adds across the double bond of 1-Penten-4-yne, the product formed will be 4,5-dibromo-1-pentene. The structure can be represented as follows: ``` CH2-Br | CH-Br | CH2-C≡C-H ``` ### Step 5: Final Product The final product of the reaction is 4,5-dibromo-1-pentene. ### Conclusion Thus, the product formed when 1-Penten-4-yne reacts with 1 mole of bromine at -80°C is 4,5-dibromo-1-pentene.
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