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Which of the following statement is corr...

Which of the following statement is correct regarding gluconic acid?

A

Gluconic acid is a dicarboxylic acid

B

Gluconic acid is obtained by oxidation of glucose with `HNO_3`

C

Gluconic acid can form cyclic (acetal/hemiacetal) structure

D

Gluconic acid is a partial oxidation product of glucose

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding gluconic acid, we need to evaluate the provided statements one by one. ### Step-by-Step Solution: 1. **Understanding Gluconic Acid Structure**: - Gluconic acid has the structure: COOH-CHOH-CHOH-CHOH-CHOH-CH2OH. It contains one carboxylic acid group (COOH) and multiple hydroxyl groups (OH). 2. **Evaluating the Statements**: - **Statement 1**: "Gluconic acid is a di-carboxylic acid." - This statement is **incorrect** because gluconic acid has only one carboxylic acid group, making it a monocarboxylic acid. - **Statement 2**: "Gluconic acid is obtained by the oxidation of glucose with ethanol." - This statement is **incorrect**. Gluconic acid is formed when glucose is oxidized, typically using bromine water, not ethanol. - **Statement 3**: "Gluconic acid can form cyclic acetyl hemiacetal structure." - This statement is **incorrect**. Gluconic acid cannot form a cyclic structure because it has a carboxylic acid group instead of an aldehyde or ketone group, which are necessary for forming cyclic structures. - **Statement 4**: "Gluconic acid is a partial oxidation product of glucose." - This statement is **correct**. Gluconic acid is indeed formed through the partial oxidation of glucose, where only one hydroxyl group is oxidized to a carboxylic acid group. 3. **Conclusion**: - The correct statement regarding gluconic acid is that it is a partial oxidation product of glucose. Therefore, the answer is **option 4**.
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