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A + NaNO2 to N2O + NaCl + 2H2O in this r...

`A + NaNO_2 to N_2O + NaCl + 2H_2O` in this reaction A can be

A

`H_2SO_4`.dil

B

`H_3PO_4`

C

`NH_2OH.HCl`

D

`dil.HCl`

Text Solution

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The correct Answer is:
To determine what compound A can be in the reaction \( A + \text{NaNO}_2 \rightarrow \text{N}_2\text{O} + \text{NaCl} + 2\text{H}_2\text{O} \), we can follow these steps: ### Step 1: Analyze the Reaction The reaction shows that compound A reacts with sodium nitrite (\( \text{NaNO}_2 \)) to produce nitrous oxide (\( \text{N}_2\text{O} \)), sodium chloride (\( \text{NaCl} \)), and water (\( \text{H}_2\text{O} \)). Notably, there are two nitrogen atoms in the product \( \text{N}_2\text{O} \). ### Step 2: Identify Possible Compounds for A Since \( \text{N}_2\text{O} \) contains nitrogen, compound A must also contain nitrogen. Possible candidates could include: - Hydroxylamine (\( \text{NH}_2\text{OH} \)) - Ammonium salts - Other nitrogen-containing compounds ### Step 3: Exclude Non-Nitrogen Compounds We can eliminate certain compounds based on the products formed: - \( \text{H}_2\text{SO}_4 \) cannot be A because no sulfur product is formed. - \( \text{H}_3\text{PO}_4 \) cannot be A because no phosphorus product is formed. ### Step 4: Test Hydroxylamine Hydrochloride Let’s consider \( \text{NH}_2\text{OH} \cdot \text{HCl} \) (hydroxylamine hydrochloride): - When \( \text{NH}_2\text{OH} \cdot \text{HCl} \) reacts with \( \text{NaNO}_2 \), it can produce \( \text{N}_2\text{O} \), \( \text{NaCl} \), and \( \text{H}_2\text{O} \). ### Step 5: Confirm the Reaction The balanced reaction would be: \[ \text{NH}_2\text{OH} \cdot \text{HCl} + \text{NaNO}_2 \rightarrow \text{N}_2\text{O} + \text{NaCl} + 2\text{H}_2\text{O} \] This confirms that \( \text{NH}_2\text{OH} \cdot \text{HCl} \) fits as compound A. ### Conclusion Thus, the compound A in the reaction is \( \text{NH}_2\text{OH} \cdot \text{HCl} \).
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