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In the reaction sequence CH -= CH + CH...

In the reaction sequence
`CH -= CH + CH -=CH overset(Cu_2Cl_2)(rarr)(A), 'B' overset(HCl)(rarr)(B)`
Will be

A

`CH_3-overset(Cl)overset(|)(CH)-C-=CH`

B

`CH_2=overset(Cl)overset(|)(C )-CH=CH_2`

C

`CH_2=CH-C-=C-Cl`

D

`CH_3-CH_2-C-=C-Cl`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we will break down the reaction sequence step by step. ### Step 1: Identify the Reactants The reactants in the reaction sequence are two molecules of acetylene (ethyne), which can be represented as: \[ \text{CH} \equiv \text{CH} + \text{CH} \equiv \text{CH} \] ### Step 2: Reaction with \( \text{Cu}_2\text{Cl}_2 \) When two moles of acetylene react in the presence of \( \text{Cu}_2\text{Cl}_2 \), a coupling reaction occurs. The acidic hydrogen from one acetylene molecule is lost, and the remaining carbon atoms form a double bond. The product formed (A) can be represented as: \[ A: \text{CH}_2 = \text{CH} - \text{C} \equiv \text{CH} \] This represents a compound with a double bond between the first two carbon atoms and a triple bond with the last carbon. ### Step 3: Reaction with HCl Next, product A is treated with hydrochloric acid (HCl). In this reaction, the \( \text{H}^+ \) from HCl will attack the triple bond because it is more reactive than the double bond. The reaction can be illustrated as follows: 1. The \( \text{H}^+ \) attacks the carbon in the triple bond, creating a carbocation. 2. The carbocation is then attacked by \( \text{Cl}^- \). The resulting product (B) after this step can be represented as: \[ B: \text{CH}_2 = \text{CH} - \text{CCl} = \text{CH}_2 \] This shows that the chlorine atom has added to the carbon that was part of the triple bond. ### Final Product Thus, the final product B is: \[ \text{CH}_2 = \text{CH} - \text{CCl} = \text{CH}_2 \] ### Summary of Products - Product A: \( \text{CH}_2 = \text{CH} - \text{C} \equiv \text{CH} \) - Product B: \( \text{CH}_2 = \text{CH} - \text{CCl} = \text{CH}_2 \)
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