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C6H5-O-CH2CH3+HI overset(Delta)(rarr)X +...

`C_6H_5-O-CH_2CH_3+HI overset(Delta)(rarr)X + Y`
Identify X and Y in the above reaction?

A

`X : C_6H_5OH, Y : CH_3CH_3`

B

`X : C_2H_5I, Y : C_6H_5CHO`

C

`X : C_6H_5I, Y : CH_3CH_2OH`

D

`X:C_6H_5OH, Y : CH_3CH_2I`

Text Solution

AI Generated Solution

The correct Answer is:
To identify the products X and Y from the reaction of C₆H₅-O-CH₂CH₃ with HI, we can follow these steps: ### Step 1: Understand the Reactants The reactant is C₆H₅-O-CH₂CH₃, which is an ether (specifically ethyl phenyl ether). When it reacts with hydroiodic acid (HI), the ether bond (C-O) can be cleaved. **Hint:** Recognize that ethers can be cleaved by strong acids like HI. ### Step 2: Protonation of the Ether When HI is added, the ether oxygen (O) gets protonated, making it a better leaving group. This results in the formation of a protonated ether. **Hint:** Protonation increases the electrophilicity of the ether, facilitating the cleavage. ### Step 3: Nucleophilic Attack The iodide ion (I⁻) from HI acts as a nucleophile. According to the SN2 mechanism, the nucleophile will attack the less hindered carbon atom. In this case, the less hindered carbon is the CH₂ group attached to the ethyl group (CH₂CH₃). **Hint:** Identify which carbon is less hindered for the nucleophilic attack. ### Step 4: Formation of Products The nucleophilic attack leads to the formation of two products: 1. X: Phenol (C₆H₅OH), which is formed from the cleavage of the ether bond. 2. Y: Ethyl iodide (CH₃CH₂I), which is formed from the other part of the ether. **Hint:** After the nucleophilic attack, consider what remains from the original ether structure. ### Conclusion Thus, the products of the reaction are: - X = Phenol (C₆H₅OH) - Y = Ethyl iodide (CH₃CH₂I) ### Final Answer X = C₆H₅OH (Phenol) Y = CH₃CH₂I (Ethyl iodide)
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