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Out of all the possible isomers of C(5)H...

Out of all the possible isomers of `C_(5)H_(11)Cl`, how many are secondary in nature?
(Exclude stereoisomers if any.)

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The correct Answer is:
To determine how many secondary isomers exist for the compound \( C_5H_{11}Cl \), we need to follow these steps: ### Step 1: Understand the definition of secondary carbon A secondary carbon is defined as a carbon atom that is bonded to two other carbon atoms. In the context of isomers of \( C_5H_{11}Cl \), we need to identify which of the carbon atoms in the structure can be classified as secondary when a chlorine atom is attached. **Hint:** Remember that for a carbon to be secondary, it must be attached to two other carbons. ### Step 2: Identify the possible carbon skeletons For \( C_5H_{11}Cl \), we can have various carbon skeletons. The main carbon chain can be linear or branched. The possible carbon skeletons include: 1. Pentane (straight chain) 2. Isopentane (branched) 3. Neopentane (more branched) **Hint:** Consider both straight-chain and branched structures when drawing the carbon skeletons. ### Step 3: Draw the structures and identify secondary carbons Now, let's draw the possible isomers and identify the secondary carbons: 1. **Isomer 1: n-Pentane** - Structure: \( CH_3-CH_2-CH_2-CH_2-CH_3 \) - Chlorine can be attached to the second carbon: \( CH_3-CH(Cl)-CH_2-CH_2-CH_3 \) (Secondary) 2. **Isomer 2: Isopentane** - Structure: \( CH_3-CH(CH_3)-CH_2-CH_3 \) - Chlorine can be attached to the second carbon: \( CH_3-CH(Cl)-CH_2-CH_3 \) (Secondary) 3. **Isomer 3: 2-Methylbutane** - Structure: \( CH_3-CH_2-CH(CH_3)-CH_3 \) - Chlorine can be attached to the second carbon: \( CH_3-CH(Cl)-CH(CH_3)-CH_3 \) (Secondary) 4. **Isomer 4: 2,2-Dimethylpropane** - Structure: \( (CH_3)_2C(CH_3)-CH_3 \) - Chlorine cannot be attached to a secondary carbon here. ### Step 4: Count the secondary isomers From the above structures, we find that the following isomers have secondary carbons: - Isomer 1: 1 secondary isomer - Isomer 2: 1 secondary isomer - Isomer 3: 1 secondary isomer Thus, there are **3 secondary isomers** of \( C_5H_{11}Cl \). ### Final Answer The total number of secondary isomers of \( C_5H_{11}Cl \) is **3**. ---
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