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if quantity of heat 1163.4 J supplied to...

if quantity of heat 1163.4 J supplied to one mole of nitrogen gas , at room temperature at constant pressure , then the rise in temperature is

A

54 K

B

28 K

C

65 K

D

40 K

Text Solution

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The correct Answer is:
To solve the problem of finding the rise in temperature when 1163.4 J of heat is supplied to one mole of nitrogen gas at constant pressure, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Molar Specific Heat at Constant Pressure (Cp)**: For a diatomic gas like nitrogen (N₂), the molar specific heat at constant pressure (Cp) can be calculated using the formula: \[ C_p = C_v + R \] where \(C_v\) is the molar specific heat at constant volume and \(R\) is the universal gas constant. 2. **Calculate Cv for Nitrogen**: The degrees of freedom (F) for a diatomic gas is 5. Therefore, we can calculate \(C_v\) as: \[ C_v = \frac{F}{2} R = \frac{5}{2} R \] 3. **Substitute Cv into the Cp Formula**: Now substituting \(C_v\) into the equation for \(C_p\): \[ C_p = \frac{5}{2} R + R = \frac{7}{2} R \] 4. **Use the Heat Equation**: The heat added to the gas is related to the change in temperature (\(\Delta T\)) by the equation: \[ Q = n C_p \Delta T \] where \(Q\) is the heat supplied, \(n\) is the number of moles, and \(\Delta T\) is the change in temperature. 5. **Substituting Known Values**: Given that \(Q = 1163.4 J\) and \(n = 1\) mole, we can rewrite the equation: \[ 1163.4 = 1 \cdot \left(\frac{7}{2} R\right) \Delta T \] 6. **Substituting the Value of R**: The value of the gas constant \(R\) is approximately \(8.314 J/(mol \cdot K)\). Thus, we have: \[ 1163.4 = \left(\frac{7}{2} \cdot 8.314\right) \Delta T \] 7. **Calculate Cp**: Calculate \(C_p\): \[ C_p = \frac{7}{2} \cdot 8.314 = 29.1 J/(mol \cdot K) \] 8. **Solving for \(\Delta T\)**: Rearranging the equation to solve for \(\Delta T\): \[ \Delta T = \frac{1163.4}{29.1} \] 9. **Final Calculation**: Performing the calculation: \[ \Delta T \approx 40 K \] ### Conclusion: The rise in temperature when 1163.4 J of heat is supplied to one mole of nitrogen gas at constant pressure is approximately **40 K**.
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