Acidified potassium permangante is dropped over sodium peroxide taken in a round bottom flask at room temperature, vigorous reaction takes place to produce :
Acidified potassium permangante is dropped over sodium peroxide taken in a round bottom flask at room temperature, vigorous reaction takes place to produce :
A
Hydrogen peroxide
B
Mixture of hydrogen and oxygen
C
A colourless gas hydrogen
D
A colourless gas dioxygen
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D
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Acidified potassium permanganate is dropped over sodium peroxide taken in a round bottom flask at room tempreture, vigorus reaction takes place to procuce:
When water is dropped over sodium peroxide, the colourless gas produced is
If hydrogen and oxygen are mixed and kept in the same vessel at room temperature, the reaction does not take place to form water because
Salts P, Q,R,S,T,U and V undergo reactions (i) to (vii) respectively. Identify the cation present in these salts on the basis of these reactions. Tabulate your answer in the formate given below. (i) When the salt Pis heated with sodium hydroxide solution a vigorous reaction takes place and a colourless gas is evolved with a pungent and suffocating smell that brings tears in our eyes. The evolved gas gives dense white fumes with a moist glass rod depped with hydrochloric acid. (ii) Addition of sodium hydroxide solution to a solution of salt Q gives a thick white precipitae which is soluble in excess of sodium hydroxide solution to form a clear solution. (iii) Addition of ammonium hydroxide solution to a solution of salt R gives a dark blue precipitate which is soluble is excess of ammonium hydroxide solution to form an intense deep blue solution. (iv) Addition of ammonium hydroxide solution to a solution of 5 gives a dirty green [bottle green] precipitate which is insoluble even in the excess of ammonium hydroxide solution. (v) Addition of ammonium hydroxide solution to a solution of T gives a reddish brown (rust precipitate] precipitate which is insoluble even in the excess of ammonium hydroxide solution. (vi) Addition of ammonium hydroxide solution to a solution of V gives a geletaneous white precipitate which is soluble in excess of ammonium hydroxide solution to form a clear solution. (vii) Addition of ammonium hydroxide solution to a solution of V gives no precipitate but it gives a chalky white precipitate with sodium hydroxide solution which is insoluble even in the excess of sodium hydroxide solution.
Name the process associated with the following (a) Dry ice is kept at room temperature and at one atmospheric pressure. (b) A drop of ink placed on the surface of water contained in a glass spreads throughout the water. (c) A potassium permanganate crystal is in a beaker and water is poured into the beaker with stirring. (d) An acetone bottle is left open and the bottle becomes empty. (e) Milk is churned to separate cream from it. (f) Settling of sand when a mixture of sand and water is left undisturbed for some time. (g) Fine beam of light entering through a small hole in a dark room. Illuminates the particles in its paths.
Diazonium salt formation and coupling reaction: When a reaction mixture of phenyl amine and nitrous acid is kept below 10^(@)C , a diazonium salt is formed. This reaction is called diazotization reaction. The diazonium ion, -N_(2)^(+) , is rather unstable and decomposes readily to nitrogen. However, delocalization of the diazonium from pi- bond electron over a benzene ring phenyl diazonium sufficiently for it to form at low temperature. The phenyl diazonium ion behaves as an electrophile, and will attack another arene molecule such as phenol. Electrophilic subsitiution takes at the 4 position, producing 4-hydroxy phenyl azobenzene. The reaction is known as coupling reaction. The compound formed is an energetically stable, yellow azo dye (the azo group is -N=N- ) The stability is due to extensive delocalisation of electrons via the nitrogen- nitrogen double bonds. Benzene diazonium chloride on reaction with phenol in weakly basic medium gives :
Diazonium salt formation and coupling reaction: When a reaction mixture of phenyl amine and nitrous acid is kept below 10^(@)C , a diazonium salt is formed. This reaction is called diazotization reaction. The diazonium ion, -N_(2)^(+) , is rather unstable and decomposes readily to nitrogen. However, delocalization of the diazonium from pi- bond electron over a benzene ring phenyl diazonium sufficiently for it to form at low temperature. The phenyl diazonium ion behaves as an electrophile, and will attack another arene molecule such as phenol. Electrophilic subsitiution takes at the 4 position, producing 4-hydroxy phenyl azobenzene. The reaction is known as coupling reaction. The compound formed is an energetically stable, yellow azo dye (the azo group is -N=N- ) The stability is due to extensive delocalisation of electrons via the nitrogen- nitrogen double bonds. The product which is a red azodye obtained on reacting benzene diazonium chloride with one of the following compounds :
Diazonium salt formation and coupling reaction: When a reaction mixture of phenyl amine and nitrous acid is kept below 10^(@)C , a diazonium salt is formed. This reaction is called diazotization reaction. The diazonium ion, -N_(2)^(+) , is rather unstable and decomposes readily to nitrogen. However, delocalization of the diazonium from pi- bond electron over a benzene ring phenyl diazonium sufficiently for it to form at low temperature. The phenyl diazonium ion behaves as an electrophile, and will attack another arene molecule such as phenol. Electrophilic subsitiution takes at the 4 position, producing 4-hydroxy phenyl azobenzene. The reaction is known as coupling reaction. The compound formed is an energetically stable, yellow azo dye (the azo group is -N=N- ) The stability is due to extensive delocalisation of electrons via the nitrogen- nitrogen double bonds. The azo dye obtained on reacting 4-aminophenol with nitrous acid (in dilute hydrochloric acid) below 10^(@)C and coupling the resulting diazonium salt with phenol is :
Write balanced chemical equations for the following: i] Reaction between 1, 2 - dibromoethane & alcoholic potassium, hydroxide. ii] Monochloro ethane is hydrolysed with aqueous KOH. iii] A mixture of sodalime and sodium acetate is heated: iv] Ethanol under high pressure & low temperature is treated with 'acidified potassium dichromate, v] Water is added to calcium carbide. vi] Ethanol reacts with sodium af room temperature.
Identify the type of reactions taking place in each of the following cases and write the balanced chemical equation for the reactions. (a) Zinc reacts with silver nitrate to produce zinc nitrate and silver. (b) Potassium iodide reacts with lead nitrate to produce potassium nitrate and lead iodide.
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