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A binary liquid solution is prepared by ...

A binary liquid solution is prepared by mixing n-heptane and ethanol. Which one of the following statements is correct regarding the behaviour of the solution? a)The solution is non-ideal, showing negative deviation from Raoult's Law b)The solution is non-ideal, showing positive deviation from Raoult's Law c)n-heptane shows positive deviation while ethanol shows negative deviation from Raoult's Law d)The solution formed is an ideal solution

A

The solution is non-ideal, showing negative deviation from Raoult's Law

B

The solution is non-ideal, showing positive deviation from Raoult's Law

C

n-heptane shows positive deviation while ethanol shows negative deviation from Raoult's Law

D

The solution formed is an ideal solution

Text Solution

Verified by Experts

The correct Answer is:
B

For this solution intermolecular interactions between n-heptane and ethanol are weaker than n-heptane n-heptane and ethanol-ethanol interactions hence the solutions of n-heptane and ethanol is non-ideal and shows positive deviation from Raoults' law.
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