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1,2-Dihydroxybenzene, 1,3-Dihydroxy benz...

1,2-Dihydroxybenzene, 1,3-Dihydroxy benzene, 1,4-Dihydroxy benzene, Hydroxy benzene.
(i), (ii), (iii), (iv)
The'increasing order of boiling points of the above mentioned alcohols is,

A

`I lt II lt III lt IV`

B

`I lt II lt IV lt III`

C

`IV lt I lt II lt III`

D

`IV lt II lt I lt III`

Text Solution

Verified by Experts

The correct Answer is:
C

The structures of the given compounds are as follows:

Boiling point increases as molecular mass increases. Thus IV has the least boiling point. This is also due to intra and intermolecular hydrogen bonding/Hence, the-correct order of boiling points is: `IV lt I lt II lt III`
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