Home
Class 12
CHEMISTRY
Assertion: Neopentyl alcohol on treatmen...

Assertion: Neopentyl alcohol on treatment with HCl gives neopentyl chloride.
Reason: Neopentyl alcohol is a tertiary alcohol.

A

If both (A) and (R) are correct and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct, but (R) is not the correct explanation of (A)

C

If (A) is correct, but (R) is incorrect

D

If both (A) and (R) are incorrect.

Text Solution

Verified by Experts

The correct Answer is:
D

Neoperityl alcohol on treatment with HCl gives-2-chloro-2-methylbutane chloride. This reaction occurs by rearrangement of initially formed less stable 1° carbocation to the more stable 3° carbocation.
Promotional Banner

Topper's Solved these Questions

  • ALCOHOL, PHENOL & ETHER

    BRILLIANT PUBLICATION|Exercise LEVEL II |100 Videos
  • ALCOHOL PHENOL AND ETHERS

    BRILLIANT PUBLICATION|Exercise LEVEL-II |40 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    BRILLIANT PUBLICATION|Exercise LEVEL III (Linked Comprehension Type) |12 Videos

Similar Questions

Explore conceptually related problems

Assertion : Neopentyl alcohol on treatment with conc. HCl gives neopenyl chloride Reason : Less stable 1^(@) and 2^(@) carbocations usually rearrange to more stable 2^(@) or 3^(@) carbocations

The reaction of neopentyl alcohol with SOCl_2 gives-

Which among the following is a tertiary alcohol?

Convert methyl alcohol Into ethylalcohol.

Denaturation of alcohol is the-

Neopentyl alcohol on treatment with HBr gives (1) neopentyl bromide (2) 2- bromo - 2- methyl butane (3) 2- methyl - 2 butene (4) 2- methyl - 1 - butene

BRILLIANT PUBLICATION-ALCOHOL, PHENOL & ETHER -LEVEL II (ASSERTION - REASON TYPE)
  1. Assertion : The cleavage of C-O bond in ethers takes place under dra...

    Text Solution

    |

  2. Assertion: Dipolemoment ofphenol is smaller than that of methanol. R...

    Text Solution

    |

  3. Assertion: Neopentyl alcohol on treatment with HCl gives neopentyl chl...

    Text Solution

    |

  4. Assertion: Phenoxide ion on treatment with an active alkyl h...

    Text Solution

    |

  5. Assertion:Phenol forms 2,4,6-tribromophenol on treatment with Br2 in c...

    Text Solution

    |

  6. Assertion: Alcohols have higher boiling points than ethers of comparab...

    Text Solution

    |

  7. Assertion: Commercially carboxylic acids are reduced to alcohols by co...

    Text Solution

    |

  8. Assertion: Ethers are not prepared by the dehydration of secondary and...

    Text Solution

    |

  9. Assertion: CO2 is non polar, while ROR is polar in nature. Reason: ...

    Text Solution

    |

  10. Assertion: t-Butyl methyl ether is not prepared by the reaction of t-b...

    Text Solution

    |

  11. Assertion: Anisole undergoes electrophilic substitution at o-and p-pos...

    Text Solution

    |

  12. Assertion: Acid catalysed dehydration of tert-butanol proceeds faster ...

    Text Solution

    |

  13. Assertion: Reaction of alcohols with SOCl2 is catalysed by the presenc...

    Text Solution

    |

  14. Assertion: Solubility of n-alcohl in water decreases with increase in ...

    Text Solution

    |

  15. Assertion: The bond angle in alcohols is slightly less than the tetr...

    Text Solution

    |

  16. Assertion: Addition reaction of water to but-1-ene in acidic medium yi...

    Text Solution

    |

  17. Assertion : Carbon oxygen bond length of phenol is slightly less than ...

    Text Solution

    |

  18. Assertion : In alcohols, the boiling point decreases with decrease in...

    Text Solution

    |

  19. Assertion : Alcohols and water are weaker acids than phenols. Reas...

    Text Solution

    |

  20. Assertion : Bromination of phenol takes place even in the absence of...

    Text Solution

    |