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‘Phenol hasa carboxylic (-COOH) group in...

‘Phenol hasa carboxylic (-COOH) group in it while alcohols have no such group. So phenol is more acidic than alcohol’:- Justify your answer.

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Paragraph Carboxylic acids are distinctly acidic because they ionize in water to give hydronium ions: RCOOH+H_(2)O hArr RCOO^(-) +H_(3)O^(+) The acidic strength depends upon the extent of ionizations of the acid and the stability of the anion formed. The acidic strength can also be expressed in terms of dissociation constant K_(a) or pK_(a) which are related as pK_(a)= -log K_(a) . Most unsubstituted carboxylic acids have K_(a) values in the range of 10^(-4) to 10^(-5) (pK_(a) =4-5) . The substitutents have marked effect on the acidic strength of carboxylic acids. Any group that stabilizes the carboxylate ion more than the carboxylic acid group will increase the acidic strength, and the group which destabilizes the carboxylate group more than the carboxylic acid group will decrease the acidic strength. In a similar manner, the electron-releasing groups makes benzoic acid weaker, while the electron-withdrawing groups make benzoic acid stronger. The ortho isomer of every substituted benzoic acid (whether electron releasing or electron withdrawing) is the strongest among the three isomers due to ortho effect. Which of the following is the weakest acid?

BODY BOOKS PUBLICATION-ALCOHOLS,PHENOLS AND ETHERS-Example
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  2. ‘Phenol has a carboxylic (-COOH) group in it while alcohols have no su...

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  3. ‘Phenol hasa carboxylic (-COOH) group in it while alcohols have no suc...

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  4. Action of alcohols and phenols towards:- Litmus paper.

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  5. Action of alcohols and phenols towards:- FeCI3 solution

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  6. Action of alcohols and phenols towards:-NaOH solution.

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  7. What happens when:-Propene is reacted with diborane and the product is...

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  8. What happens when:- Propan-1-oI is treated with ethanoic acid in prese...

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  9. A compóund A with molecular formula C4 H10O. on oxidation forms compou...

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  10. Complete the following equations:- R-CH=CH2 overset(Hg(OAC)2.H2O) unde...

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  11. Identify A, B and C:-CH3CH2-CH2I overset (aIcKOH)(rarr)A overset (H2O ...

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  12. How will you prepare aspirin from phenol ?

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  13. A student observes the following order for the acid-strength of water,...

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  14. Convert methyl alcohol Into ethylalcohol.

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  15. One student argues that he can prepare propane-2-ol from acetaldehyde ...

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  16. One student argues that he can prepare propane-2-ol from acetaldehyde ...

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  17. Identify A, B, in the following :

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  18. Give the equations of reactions for the preparation of phenol from cum...

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  19. Three alcohols are given below, ethanol, 2-propanol, and 2-methyl-2-pr...

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  20. Three alcohols are given below, ethanol, 2-propanol, and 2-methyl-2-pr...

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