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The unshared pair of electrons on a cyan...

The unshared pair of electrons on a cyanide ion can act as

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Assertion : Cyanides R - C -= N : are very much weaker bases than aliphatic bases. Reason : This is due to the fact that as the nitrogen atom becomes more multiply bonded, the lone pair of electrons are accommodated in an orbital that has more 'S' character. The electron pair is thus drawn closer to the nitrogen nucleus, and held more lightly by it.

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BODY BOOKS PUBLICATION-AMINES-EXAMPLE
  1. Gabriel synthesis Is used for the synthesis of

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  2. Benzene diazonium chloride on heating in water gives mainly

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  3. The unshared pair of electrons on a cyanide ion can act as

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  4. The indicator that is obtained by coupling the diazonium salt of sulph...

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  5. Complete the following reaction. C6H5N2Cl+KI rarr …………………………..

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  6. Which one of the will be most basic ?

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  7. The amine which will not liberate nitrogen on reaction with nitrous ac...

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  8. Amines are basic. Arrange the following amines in the increasing order...

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  9. Which of the following compounds exist as a Zwitter ion ?

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  10. A primary amine that can be obtained both by the reduction of cyanides...

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  11. In secondary and tertiary amines when two or more alkyl groups are dif...

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  12. Observe the relationship between the first two terms and fill in the b...

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  13. Complete the following reactions.C6H5-NO2 overset (Sn//HCl)(rarr)

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  14. Complete the following reactions.C6H5N2Cl+H2O overset (Heat)(rarr)

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  15. Ammonia is a base because it has a lone pair of electrons. Predict the...

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  16. Ammonia is a base because it has a lone pair of electrons. Predict the...

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  17. Identify the main product and name the reactions.When ethylamine treat...

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  18. Identify the main product and name the reactions.When amide treated wi...

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  19. A compound which exists as a Zwitter ion is formed when aniline is tre...

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  20. Give one chemical test to distinguish between CH3CH2NH2 and (CH3)2NH.

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