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The indicator that is obtained by coupli...

The indicator that is obtained by coupling the diazonium salt of sulphanilic acid with N, N - dimethyl aniline is

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Arene diazonium salts are more stable than alkanediazonium salts due to dispersal of the positive charge on the benzene ring. Obviously, electron-donating groups favour diazotisation by retarding the decomposition of diazonium salts to phenyl cation. The high reactivity of arenediazonium salts is due to the excellent leaving ability of the diazo group as N_2 gas. Consider the following ions: The reactivity of these ions towards azo coupling reactions under similar conditions is

Arene diazonium salts are more stable than alkanediazonium salts due to dispersal of the positive charge on the benzene ring. Obviously, electron-donating groups favour diazotisation by retarding the decomposition of diazonium salts to phenyl cation. The high reactivity of arenediazonium salts is due to the excellent leaving ability of the diazo group as N_2 gas. Which of the following arylamines undergoes diazotisation most readily?

Give one chemical test to distinguish between the following pairs of compounds i. Methylamine and dimethyl amine ii. Secondary and tertiary AMINES iii. Ethylamine and aniline iv. Aniline and benzylamine v. Aniline and N- methyl aniline

How many of the following amines will undergo diazotisation? tert-Butylamine, ethanamine, aniline, N-methylaniline, p-toluidine, m-chloroaniline, 2-phenylethanamine o-anisidihe, 2,4,6-tribromoaniline.

BODY BOOKS PUBLICATION-AMINES-EXAMPLE
  1. Benzene diazonium chloride on heating in water gives mainly

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  2. The unshared pair of electrons on a cyanide ion can act as

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  3. The indicator that is obtained by coupling the diazonium salt of sulph...

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  4. Complete the following reaction. C6H5N2Cl+KI rarr …………………………..

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  5. Which one of the will be most basic ?

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  6. The amine which will not liberate nitrogen on reaction with nitrous ac...

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  7. Amines are basic. Arrange the following amines in the increasing order...

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  8. Which of the following compounds exist as a Zwitter ion ?

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  9. A primary amine that can be obtained both by the reduction of cyanides...

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  10. In secondary and tertiary amines when two or more alkyl groups are dif...

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  11. Observe the relationship between the first two terms and fill in the b...

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  12. Complete the following reactions.C6H5-NO2 overset (Sn//HCl)(rarr)

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  13. Complete the following reactions.C6H5N2Cl+H2O overset (Heat)(rarr)

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  14. Ammonia is a base because it has a lone pair of electrons. Predict the...

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  15. Ammonia is a base because it has a lone pair of electrons. Predict the...

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  16. Identify the main product and name the reactions.When ethylamine treat...

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  17. Identify the main product and name the reactions.When amide treated wi...

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  18. A compound which exists as a Zwitter ion is formed when aniline is tre...

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  19. Give one chemical test to distinguish between CH3CH2NH2 and (CH3)2NH.

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  20. Give the structure of following compounds: N-Methylethanmine

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