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Which of the following sets of quantum n...

Which of the following sets of quantum numbers are NOT possible?
n=2, l=2, `m_I=0`, `m_s=+1/2`
n=1, l=0, `m_I=0`, `m_s=-1/2`
n=3, l=2, `m_I=-3`, `m_s=+1/2`
n=2, l=1, `m_I=1`, `m_s=+1/2` Justify your answer.

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