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Toulene reacts with bromine and iron to ...

Toulene reacts with bromine and iron to give a mixture of three isomeric monobromo products, while with bromine in light it gives exclusively the fourth isomer. Justify the observation.

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Paragraph An organic compound A(C_(9)H_(6)O_(3)) does not react with aqueous solution of NaHCO_(3) as well as does not change the colour of litmus paper. Aon acid hydrolysis gives B(C_(9) H_(8)O_(4)) as major product whereas A on treatment with one equivalent of methanol in acidic medium gives C(C_(10)H_(10)O_(4)) as the major product (other minor isomer of C is also formed). B on heating with sodalime gives toluene. Answer the following questions based on the above information. The structure of product C is

Paragraph An organic compound A(C_(9)H_(6)O_(3)) does not react with aqueous solution of NaHCO_(3) as well as does not change the colour of litmus paper. Aon acid hydrolysis gives B(C_(9) H_(8)O_(4)) as major product whereas A on treatment with one equivalent of methanol in acidic medium gives C(C_(10)H_(10)O_(4)) as the major product (other minor isomer of C is also formed). B on heating with sodalime gives toluene. Answer the following questions based on the above information. The structure of A satisfying above conditions is