Home
Class 11
CHEMISTRY
Enthalpy of neutralization of HCl by NaO...

Enthalpy of neutralization of HCl by NaOH is `-55.84` kJ/mol and by `NH_(4)OH` is `51.34` kJ/mol. The enthalpy of ionization of `NH_(4)OH` is :

A

107.18 kJ/mol

B

4.5 kJ/mol

C

`-4.5` kJ/mol

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
B

`DeltaH_("neut")`.
`=DeltaH_("ionization")+Delta_(r )H(H^(+)+OH^(-)rarrH_(2)O)`
`implies" "-51.34 = x - 55.84`
So, `" "DeltaH_("ionization") " or "x=4.5 " kJ"//"mol"`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    NARENDRA AWASTHI|Exercise Level 3 - One Or More Answers Are Correct|1 Videos
  • THERMODYNAMICS

    NARENDRA AWASTHI|Exercise Level 3 - Match The Column|2 Videos
  • THERMODYNAMICS

    NARENDRA AWASTHI|Exercise Level 2 (Q.1 To Q.30)|1 Videos
  • STOICHIOMETRY

    NARENDRA AWASTHI|Exercise Level 3 - Subjective Problems|20 Videos

Similar Questions

Explore conceptually related problems

If enthalpy of neutralisation of HCl by NaOH is -57 kJ " mol"^(-1) and with NH_(4)OH is -50 kJ " mol"^(-1) . Calculate enthalpy of ionisation of NH_(4)OH (aq).

Enthalpy of neutralzation is defined as the enthalpy change when 1 mole of acid / / base is completely neutralized by base // acid in dilute solution . For Strong acid and strong base neutralization net chemical change is H^(+) (aq)+OH^(-)(aq)to H_(2)O(l) Delta_(r)H^(@)=-55.84KJ//mol DeltaH_("ionization")^(@) of aqueous solution of strong acid and strong base is zero . when a dilute solution of weak acid or base is neutralized, the enthalpy of neutralization is somewhat less because of the absorption of heat in the ionzation of the because of the absorotion of heat in the ionization of the weak acid or base ,for weak acid /base DeltaH_("neutrlzation")^(@)=DeltaH_("ionization")^(@)+ Delta _(r)H^(@)(H^(+)+OH^(-)to H_(2)O) If enthalpy of neutralization of CH_(3)COOH by NaOH is -49.86KJ // mol then enthalpy of ionization of CH_(3)COOH is:

The enthalpy of neutralization of a Weak monoprotic acid (HA) in 1 M solution with a strong base is -55.95 KJ/mol . If the unionized acid required 1.4 KJ/mol heat for it's comptate ionzatation and enthalpy of netralization of the strong monobasic acid with a strong monoacidic base is -57.3 KJ/mol . What is the % ionzation of the weak acid in molar solution ?

If the enthalpy of formation and enthalpy of solution of HCl (g) are-92.3kj /mol and -75.14kJ/mol respectively then find the enthalpy of Cl^(-) (aq):

The standard enthalpy of formation of octane (C_(8)H_(18)) is -250kJ //mol . Calculate the enthalpy of combustion of C_(8)H_(18) . The enthalpy of formation of CO_(2)(g) and H_(2)O(l) are -394 kJ//mol and -286kJ//mol respectively.

The enthalpy change for the reaction N2(g) + 3 H2(g) → 2 NH3(g) is -91.8 kJ at 298 K. Calculate the enthalpy of formation of ammonia?

Calculate the enthalpy of hydration of BaCl_(2) to BaCl_(2).2H_(2)O (s) given that the enthalpy of solution of BaCl_(2) (s) is - 20.6 kJ mol^(-1) and that of BaCl_(2).2H_(2)O(s) is + 8.8 KJ mol^(-1) .

Calculate the enthalpy change in the reaction, 4NH_(3) + 3O_(2) to 2N_(2) + 6H_(2) O at 298 K,given that the enthalpy of formation at 298 K for NH_(3) and H_(2)O are - 46.0 and - 286.0 KJ mol^(-1) respectively.

Calculate the enthaply change in the reaction, CH_(4)(g) + 2O_(2)(g) to CO_(2)(g) + 2H_(2)O (i)The enthalpy change of formation of CH_(4) (g), CO_(2)(g) and H_(2)O (i) are - 74.8 kj mol^(-1), -393.5 KJ mol^(-1) and - 286 KJ mol^(-1) respectively.

NARENDRA AWASTHI-THERMODYNAMICS-Exercise
  1. Write iupac name of CH3-CH = CH -COOH

    Text Solution

    |

  2. What do you mean by meta position?

    Text Solution

    |

  3. Enthalpy of neutralization of HCl by NaOH is -55.84 kJ/mol and by NH(4...

    Text Solution

    |

  4. Which of the following equations are exothermic or endothermic? N2(g)...

    Text Solution

    |

  5. Which of the following is not correct? Robert Brown discovered the c...

    Text Solution

    |

  6. Substance A(2)B(g) can undergoes decomposition to form two set of prod...

    Text Solution

    |

  7. Write structure of diphenylmethane.

    Text Solution

    |

  8. The enthalpy change for the following reaction is 368 kJ. Calculate th...

    Text Solution

    |

  9. Calculate the enthalpy change for the reaction H(2)(g) + Cl(2)(g) to ...

    Text Solution

    |

  10. The table given below lists the bond dissociation energy (E("diss")) f...

    Text Solution

    |

  11. Write iupac names of the following: CH2=CH-CH(CH3) -CH=CH-CH=CH2

    Text Solution

    |

  12. Write iupac names of the following: CH=C-CH(CH3)-CH=CH2

    Text Solution

    |

  13. Write iupac names of the following: CH3-C=C-CH(CH3)2

    Text Solution

    |

  14. A heating coil is immersed in a 100 g sample of H(2)O (l) at a 1 atm ...

    Text Solution

    |

  15. A rigid and insulated tank of 3m^(3) volume is divided into two compar...

    Text Solution

    |

  16. Write iupac names of the following: Cl2-CH-CH2-OH

    Text Solution

    |

  17. For an ideal gas (C(p,m))/(C(v,m))=gamma. The molecular mass of the ga...

    Text Solution

    |

  18. 1 mole of an ideal gas A(C(v.m)=3R) and 2 mole of an ideal gas B are...

    Text Solution

    |

  19. Calculate the work done by the system in an irreversible (single step)...

    Text Solution

    |

  20. Write iupac names of the following: Br-CH2-CH2-CHO

    Text Solution

    |