Home
Class 11
CHEMISTRY
1 mole of an ideal gas A(C(v.m)=3R) and ...

1 mole of an ideal gas `A(C_(v.m)=3R)` and 2 mole of an ideal gas B are `((C_(v,m)=(3)/(2)R)` taken in a container and expanded reversible and adiabatically from 1 litre of 4 letre starting from initial temperature of 320 K. `DeltaE ` or `DeltaU` for the process is :

A

`240` R

B

240 R

C

480 R

D

`-960` R

Text Solution

Verified by Experts

The correct Answer is:
D

`"Av. C"_(V,m)=(n_(1)C_(V,m_(1))+n_(2)C_(V,m_(2)))/(n_(1)+n_(2))=2R`
for adiabatic process dU = dW
`(dT)/(T)=-(R)/(C_(V,m))((dV)/(V))`
`n_(1)C_(V,m_(1))dT+n_(2)C_(V,m_(2))dT`
`=-(n_(1)RT+n_(2)RT)xx(dV)/(V)`
`"ln"(T_(2))/(T_(1))=-(1)/(2)"ln"((V_(2))/(V_(1)))`
`rArr" "T_(2)=320xx((1)/(4))^(1//2)`
= 160 K
`DeltaU=(n_(1)C_(V,m_(1))+n_(2)C_(V,m_(2)))DeltaT=-960R`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    NARENDRA AWASTHI|Exercise Level 3 - One Or More Answers Are Correct|1 Videos
  • THERMODYNAMICS

    NARENDRA AWASTHI|Exercise Level 3 - Match The Column|2 Videos
  • THERMODYNAMICS

    NARENDRA AWASTHI|Exercise Level 2 (Q.1 To Q.30)|1 Videos
  • STOICHIOMETRY

    NARENDRA AWASTHI|Exercise Level 3 - Subjective Problems|20 Videos

Similar Questions

Explore conceptually related problems

A gas (C_(v.m) = (5)/(2)R) behaving ideally is allowed to expand reversibly and adiabatically from 1 litre to 32 litre. Its initial temperature is 327^(@)C . The molar enthalpy change (in J//mol ) for the process is :

0.5 mole each of two ideal gases A (C_(v,m)=(5)/(2)R) and B (C_(v,m)=3R) are taken in a container and expanded reversibly and adiabatically, during this process temperature of gaseous mixture decreased from 350 K to 250 K. Find DeltaH (in cal/mol) for the process :

One mole of an ideal gas (C_(v,m)=(5)/(2)R) at 300 K and 5 atm is expanded adiabatically to a final pressure of 2 atm against a constant pressure of 2 atm. Final temperature of the gas is :

2 mole of an ideal monoatomic gas undergoes a reversible process for which PV^(2)=C . The gas is expanded from initial volume of 1 L to final volume of 3 L starting from initial temperature of 300 K. Find DeltaH for the process :

With what minimum pressure (in kPa), a given volume of an ideal gas (C_(p,m)=7//2R) originally at 400 K and 100 kPa pressure can be compressed irreversibly adiabatically in order to raise its temperature to 600 K :

When two moles of an ideal gas (C_(p.m.)=(5)/(2)R) heated form 300K to 600K at constant pressure, the change in entropy of gas (DeltaS) is:

If one mole of an ideal gas (C_(p.m.)=(5)/(2)R) is expanded isothermally at 300K until it’s volume is tripled, then change in entropy of gas is:

The work done in adiabatic compression of 2 mole of an ideal monoatomic gas by constant external pressure of 2 atm starting from initial pressure of 1 atm and initial temperature of 30 K(R=2 cal//"mol-degree")

When two moles of ideal gas (C_v = 3/2R) heated from 300 K to 600 K at constant volume, calculate DeltaS_(gas) :

10 litre of a non linear polyatomic ideal gas at 127^(@)C and 2 atm pressure is suddenly released to 1 atm pressure and the gas expanded adiabatically against constant external pressure. The final temperature and volume of the gas respectively are.

NARENDRA AWASTHI-THERMODYNAMICS-Exercise
  1. Write iupac names of the following: Cl2-CH-CH2-OH

    Text Solution

    |

  2. For an ideal gas (C(p,m))/(C(v,m))=gamma. The molecular mass of the ga...

    Text Solution

    |

  3. 1 mole of an ideal gas A(C(v.m)=3R) and 2 mole of an ideal gas B are...

    Text Solution

    |

  4. Calculate the work done by the system in an irreversible (single step)...

    Text Solution

    |

  5. Write iupac names of the following: Br-CH2-CH2-CHO

    Text Solution

    |

  6. A gas (C(v.m) = (5)/(2)R) behaving ideally is allowed to expand revers...

    Text Solution

    |

  7. Two mole of an ideal gas is heated at constant pressure of one atmosp...

    Text Solution

    |

  8. 10 mole of an ideal gas is heated at constant pressure of one atmosphe...

    Text Solution

    |

  9. For polytropic process PV^(x) = constant, molar heat capacity (C(m)) o...

    Text Solution

    |

  10. 2 mole of an ideal monoatomic gas undergoes a reversible process for w...

    Text Solution

    |

  11. Calculate DeltaS for 3 mole of a diatomic ideal gas which is heated an...

    Text Solution

    |

  12. One mole of an ideal monoatomic gas at 27^(@)C is subjected to a rever...

    Text Solution

    |

  13. Two moles of an ideal gas is expanded irreversibly and isothermally at...

    Text Solution

    |

  14. For a perfectly crystalline solid C(p,m)=aT^(3)+bT, where a and b are ...

    Text Solution

    |

  15. What are hybridisation states of each carbon atom in the following com...

    Text Solution

    |

  16. Combustion of sucrose is used by aerobic organisms for providing energ...

    Text Solution

    |

  17. For the hypothetical reaction A(2)(g)+B(2)(g) to 2AB(g) DeltaG(r)^...

    Text Solution

    |

  18. Write structure of cyclopentanone.

    Text Solution

    |

  19. Write structure of 3-hydroxybutanoic acid.

    Text Solution

    |

  20. Write structure of cyclopropane

    Text Solution

    |