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Indicate the sigma and pi bond in the fo...

Indicate the sigma and pi bond in the following molecules : C6H6

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The correct Answer is:
C

`(1)/(2)N_(2)(g)+(3)/(2)H_(2)(g)rarrNH_(3)(g)`
Let B.E. of `N-=N` is x
`-46 = (x)/(2)+(3)/(2)xx436 - 3xx393 implies x = 958`
`N_(2)H_(4)(l) rarrN_(2)(g)+2H_(2)(g),`
`Delta_(r )H=-50 " kJ"//"mol"`
`Delta_(r)H=[(Delta_("vap")H(N_(2)H_(4),l)),(+4xxB.E.(N-H)),(+B.E.(N-N))]`
`-((B.E.(N-=N)),(+2B.E.(H-H)))`
`-50 =(18+4xx393+y)-(958 + 2xx436)`
`-50=(1590+y)-(1830)`
`B.E. (N-N) or y = 190 kJ/mol
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NARENDRA AWASTHI-THERMODYNAMICS-Exercise
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  2. What are hybridisation states of each carbon atom in the following com...

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  3. Indicate the sigma and pi bond in the following molecules : C6H6

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  4. Indicate the sigma and pi bond in the following molecules : C6H12 (cyc...

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  5. Indicate the sigma and pi bond in the following molecules : CH2Cl2

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  6. Indicate the sigma and pi bond in the following molecules : CH2=C=CH2

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  7. Indicate the sigma and pi bond in the following molecules : CH3NH2

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  8. Indicate the sigma and pi bond in the following molecules : HCONHCH3

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  9. Write bond line formula for ethylene glycol

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  10. Write bond line formula for 2-methylbutanal

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  11. Write bond line formula for heptan-3-one

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  13. Write iupac name of CH3-CH2-CH2-C6H5

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  14. Write iupac name of CH3-CH(Cl )-CH3

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  15. Write iupac name of C6H5-CH2-C6H5

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  17. Give the iupac names of the following compound : Cl-CH2-CH2-CHO

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