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Enthalpy of neutralzation is defined as ...

Enthalpy of neutralzation is defined as the enthalpy change when 1 mole of acid /base is completely neutralized by base `//`acid in dilute solution .
For Strong acid and strong base neutralization net chemical change is
`H^(+) (aq)+OH^(-)(aq)to H_(2)O(l)`
`Delta_(r)H^(@)=-55.84KJ//mol`
`DeltaH_("ionization")^(@)` of aqueous solution of strong acid and strong base is zero .
when a dilute solution of weak acid or base is neutralized, the enthalpy of neutralization is somewhat less because of the absorption of heat in the ionzation of the because of the absorotion of heat in the ionization of the weak acid or base ,for weak acid /base
`DeltaH_("neutrlzation")^(@)=DeltaH_("ionization")^(@)+ Delta _(r)H^(@)(H^(+)+OH^(-)to H_(2)O)`
What is `DeltaH^(@)` for complate neutralization of strong diacidic base `A(OH)_(2)by HNO_(3)`?

A

`-55.84` kJ/mol

B

`111.68` kJ/mol

C

55.84 kJ/mol

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
B

`Delta_(r )H=2xx(-55.84)=-111.68 " kJ"`
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NARENDRA AWASTHI-THERMODYNAMICS-Exercise
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  2. Enthalpy of neutralzation is defined as the enthalpy change when 1 mol...

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  3. Enthalpy of neutralzation is defined as the enthalpy change when 1 mol...

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  4. Enthalpy of neutralzation is defined as the enthalpy change when 1 mol...

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  5. Gibbs Helmholtz equation relates the enthalpy, entropy and free energy...

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  6. Gibbs Helmholtz equation relates the enthalpy, entropy and free energy...

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  7. Gibbs Helmholtz equation relates the enthalpy, entropy and free energy...

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  8. Identify the intensive quantities from the following :

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  9. Identify the extensive quantities from the following :

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  10. Identify the state functions from the following :

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  11. Which of the following statementl is/are correct as per IUPAC sign con...

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  12. In an isothermal irreversible expansion of an ideal gas as per IUPAC s...

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  13. In reversible isothermal expansion of an ideal gas :

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  14. An adiabatic process is that process in which :

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  15. The density of the ideal gas is given by

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  16. One mole of an ideal gas is subjected to a two step reversible process...

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  17. Which of the following is/are correct?

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  18. DeltaHltDeltaU for the reaction(s) :

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  19. Which of the following conditions will always lead to a non-spontaneou...

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  20. For a process to be spontaneous at constant T and P :

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