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Gibbs Helmholtz equation relates the ent...

Gibbs Helmholtz equation relates the enthalpy, entropy and free energy change of the process at constant pressure and temperature as
`DeltaG=DeltaH-TDeltaS " (at constant P, T)"`
In General the magnitude of `DeltaH` does not change much with the change in temperature but the terms `TDeltaS` changes appreciably. Hence in some process spontaneity is very much dependent on temperature and such processes are generally known as entropy driven process.
For the reaction at 298 K, `A_(2)B_(4)rarr2AB_(2)`
`DeltaH=2" kJ"` and `DeltaS` = 20 J/K at constant P and T, the reaction will be

A

spontaneous and entropy driven

B

spontaneous and enthalpy driven

C

non-spontaneous

D

at equilibrium

Text Solution

Verified by Experts

The correct Answer is:
A

`(DeltaG)_(PT)=2000-(20xx298)`
`=-3960 " J"//"mol"`
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NARENDRA AWASTHI-THERMODYNAMICS-Exercise
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  6. Identify the intensive quantities from the following :

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  7. Identify the extensive quantities from the following :

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  8. Identify the state functions from the following :

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  9. Which of the following statementl is/are correct as per IUPAC sign con...

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  10. In an isothermal irreversible expansion of an ideal gas as per IUPAC s...

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  11. In reversible isothermal expansion of an ideal gas :

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  12. An adiabatic process is that process in which :

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  13. The density of the ideal gas is given by

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  14. One mole of an ideal gas is subjected to a two step reversible process...

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  15. Which of the following is/are correct?

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  16. DeltaHltDeltaU for the reaction(s) :

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  17. Which of the following conditions will always lead to a non-spontaneou...

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  18. For a process to be spontaneous at constant T and P :

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  19. Write iupac name of CH3-CH(OH)-CH2OH

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  20. Give the iupac names of the following compound : CH3-CH2-CH(CH3)-CH2-C...

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