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dpi -ppi bond is present in...

`dpi -ppi` bond is present in

A

`CO_(3)^(2-)`

B

`PO_4^(3-)`

C

`NO_3^(-)`

D

`NO_2^(-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine where a Dπ-Pπ bond is present, we need to analyze the electronic configurations of the relevant elements. ### Step-by-Step Solution: 1. **Identify the Elements**: The question involves identifying the presence of a Dπ-Pπ bond in certain molecules, specifically looking at carbon, phosphorus, and nitrogen. 2. **Electronic Configuration of Carbon**: - Carbon has an atomic number of 6. - Its electronic configuration is: \[ 1s^2 \, 2s^2 \, 2p^2 \] - Since carbon does not have any d-orbitals in its valence shell (the highest energy level is n=2), it cannot form a Dπ-Pπ bond. 3. **Electronic Configuration of Phosphorus**: - Phosphorus has an atomic number of 15. - Its electronic configuration is: \[ 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^3 \] - Phosphorus has d-orbitals available in the 3rd shell (3d), allowing for the possibility of forming a Dπ-Pπ bond. 4. **Electronic Configuration of Nitrogen**: - Nitrogen has an atomic number of 7. - Its electronic configuration is: \[ 1s^2 \, 2s^2 \, 2p^3 \] - Similar to carbon, nitrogen does not have d-orbitals in its valence shell, thus it cannot form a Dπ-Pπ bond. 5. **Conclusion**: - Since only phosphorus has the necessary d-orbitals to form a Dπ-Pπ bond, the correct answer is that the Dπ-Pπ bond is present in phosphorus. ### Final Answer: The Dπ-Pπ bond is present in phosphorus.

To determine where a Dπ-Pπ bond is present, we need to analyze the electronic configurations of the relevant elements. ### Step-by-Step Solution: 1. **Identify the Elements**: The question involves identifying the presence of a Dπ-Pπ bond in certain molecules, specifically looking at carbon, phosphorus, and nitrogen. 2. **Electronic Configuration of Carbon**: - Carbon has an atomic number of 6. ...
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