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The rate constant for a reaction is 10.8...

The rate constant for a reaction is `10.8 xx 10^(-3) "mol L"^(-1)`. The reaction obeys:

A

First order

B

Zero order

C

Second order

D

All are wrong

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The correct Answer is:
To determine the order of the reaction based on the given rate constant, we can follow these steps: ### Step 1: Understand the Units of the Rate Constant The rate constant (k) is given as \(10.8 \times 10^{-3} \, \text{mol L}^{-1} \, \text{s}^{-1}\). The units of the rate constant depend on the order of the reaction. ### Step 2: Write the General Rate Law Expression The rate of a reaction can be expressed as: \[ \text{Rate} = k \cdot [\text{Reactant}]^n \] where \(k\) is the rate constant, \([\text{Reactant}]\) is the concentration of the reactant, and \(n\) is the order of the reaction. ### Step 3: Identify the Units of Rate and Concentration - The rate of the reaction is typically expressed in terms of concentration change over time, which has units of: \[ \text{Rate} = \frac{\text{mol L}^{-1}}{\text{s}} \quad (\text{moles per liter per second}) \] - The concentration of the reactant is expressed in: \[ [\text{Reactant}] = \text{mol L}^{-1} \] ### Step 4: Set Up the Equation for Units From the rate law expression, we can rearrange it to express the units of \(k\): \[ \text{Rate} = k \cdot [\text{Reactant}]^n \implies k = \frac{\text{Rate}}{[\text{Reactant}]^n} \] Substituting the units, we get: \[ k = \frac{\text{mol L}^{-1} \, \text{s}^{-1}}{(\text{mol L}^{-1})^n} \] ### Step 5: Simplify the Units of k This can be simplified to: \[ k = \text{mol L}^{-1} \, \text{s}^{-1} \cdot \text{mol}^{-n} \, \text{L}^n = \text{mol}^{1-n} \, \text{L}^{-1+n} \, \text{s}^{-1} \] ### Step 6: Compare the Units Now, we compare the units of \(k\) with the given units \( \text{mol L}^{-1} \, \text{s}^{-1} \): \[ \text{mol}^{1-n} \, \text{L}^{-1+n} \, \text{s}^{-1} = \text{mol}^{1} \, \text{L}^{-1} \, \text{s}^{-1} \] From this comparison, we can set up the following equations: 1. \(1 - n = 1\) (from the mol units) 2. \(-1 + n = -1\) (from the L units) ### Step 7: Solve for n From the first equation: \[ 1 - n = 1 \implies n = 0 \] Thus, the order of the reaction is \(n = 0\). ### Conclusion The order of the reaction is **0**. ---

To determine the order of the reaction based on the given rate constant, we can follow these steps: ### Step 1: Understand the Units of the Rate Constant The rate constant (k) is given as \(10.8 \times 10^{-3} \, \text{mol L}^{-1} \, \text{s}^{-1}\). The units of the rate constant depend on the order of the reaction. ### Step 2: Write the General Rate Law Expression The rate of a reaction can be expressed as: \[ ...
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