Home
Class 12
CHEMISTRY
The rate law for the single step reactio...

The rate law for the single step reaction `2A + B to X` given by

A

Rate `= K [A][B]`

B

Rate `= K [A]^(2)[B]`

C

Rate `= K [2A][B]`

D

Rate `= K [A]^(2) [B]^(0)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the rate law for the single step reaction \(2A + B \to X\), we can follow these steps: ### Step 1: Identify the reactants and their stoichiometry The reaction involves two reactants: \(A\) and \(B\). The stoichiometric coefficients from the balanced equation are: - For \(A\): 2 - For \(B\): 1 ### Step 2: Understand the relationship between stoichiometry and reaction order For elementary reactions (which this is, since it occurs in a single step), the order of the reaction with respect to each reactant is equal to its stoichiometric coefficient in the balanced equation. ### Step 3: Write the rate law expression The rate law can be expressed as: \[ \text{Rate} = k [A]^m [B]^n \] where: - \(k\) is the rate constant, - \(m\) is the order with respect to \(A\), - \(n\) is the order with respect to \(B\). ### Step 4: Assign the orders based on stoichiometry From the stoichiometry: - The order with respect to \(A\) (m) is 2 (since the coefficient of \(A\) is 2). - The order with respect to \(B\) (n) is 1 (since the coefficient of \(B\) is 1). ### Step 5: Combine the orders to write the complete rate law Substituting the values of \(m\) and \(n\) into the rate law expression gives: \[ \text{Rate} = k [A]^2 [B]^1 \] or simply: \[ \text{Rate} = k [A]^2 [B] \] ### Step 6: Determine the overall order of the reaction The overall order of the reaction is the sum of the individual orders: \[ \text{Overall order} = m + n = 2 + 1 = 3 \] ### Final Answer Thus, the rate law for the reaction \(2A + B \to X\) is: \[ \text{Rate} = k [A]^2 [B] \] and the overall order of the reaction is 3. ---

To determine the rate law for the single step reaction \(2A + B \to X\), we can follow these steps: ### Step 1: Identify the reactants and their stoichiometry The reaction involves two reactants: \(A\) and \(B\). The stoichiometric coefficients from the balanced equation are: - For \(A\): 2 - For \(B\): 1 ### Step 2: Understand the relationship between stoichiometry and reaction order ...
Promotional Banner

Topper's Solved these Questions

  • MOLECULARITY

    PHYSICS WALLAH|Exercise NEET Past 5 Years Questions|30 Videos
  • MOLECULARITY

    PHYSICS WALLAH|Exercise NEET Past 5 Years Questions|30 Videos
  • HYDROGEN

    PHYSICS WALLAH|Exercise LEVEL-2|58 Videos
  • ORGANIC CHEMISTRY

    PHYSICS WALLAH|Exercise NEET PAST 5 YEARS QUESTIONS |13 Videos

Similar Questions

Explore conceptually related problems

The rate law for the single-step reaction, 2A + B to 2C , is given by:

The rate law for a reaction A + B to C + D is given by the expression k[A]. The rate of reaction will be

The rate law for elecentary reaction A+2B to C +2D will be _.

Rate law for the reaction A + 2B to C is found to be

The rate law for a reaction between A and B is given by rate = k[A]^(n)[B]^(m) . On doubling the concentration of A and halving the concentration of B , the ratio of the new rate to the earlier rate of the reaction becomes

PHYSICS WALLAH-MOLECULARITY -LEVEL-2
  1. The rate constant for a reaction is 10.8 xx 10^(-3) "mol L"^(-1). The ...

    Text Solution

    |

  2. Activation energy of a chemical reaction can be determined by

    Text Solution

    |

  3. The rate law for the single step reaction 2A + B to X given by

    Text Solution

    |

  4. The rate constant of reaction 2A+B to C is 2.57 xx 10^(-1) "L mol"^(-1...

    Text Solution

    |

  5. For a first order reaction the plot of ‘t’ against log c gives a strai...

    Text Solution

    |

  6. A graph plotted between log t(50%) vs log concentration is a straight ...

    Text Solution

    |

  7. K for a zero order reaction is 2 xx 10^(-2) "mol L"^(-1) "sec"^(-1). I...

    Text Solution

    |

  8. In a certain reaction, 10% of the reactant decomposes in one hour, 20%...

    Text Solution

    |

  9. The given reaction 2 "FeCI"3 + "SnCI"2 to 2"FeCI"2 + "SnCI"4 is an...

    Text Solution

    |

  10. The rate constant for a reaction is ("In 2")/(10) " min"^(-1). What wi...

    Text Solution

    |

  11. For the reaction A rarr" Product, "-(d[A])/(dt)=k and at different tim...

    Text Solution

    |

  12. Consider the reaction 2A(g) rarr 3B(g) + C(g). Starting with pure A in...

    Text Solution

    |

  13. Let there be as first-order reaction of th type. A to B + C Let us ass...

    Text Solution

    |

  14. Rate of which reactions increases with temperature:

    Text Solution

    |

  15. The rate constant, the activation energy and the Arrhenius parameter o...

    Text Solution

    |

  16. The activation energy for the forward reaction X rarr Y is 60 kJ mol^(...

    Text Solution

    |

  17. For a given reaction, energy of activation for forward reaction (E(af)...

    Text Solution

    |

  18. In the reaction NH(4)NO(2)(aq.) rarr N(2)(g) + 2H(2)O(l) the volume of...

    Text Solution

    |

  19. In a first order reaction A to B, if k is rate constant and initial co...

    Text Solution

    |

  20. For a reaction following n^(th) order kinetics, the half life (t(1//2)...

    Text Solution

    |